Optimization of methylene blue photodegradation by Cr-PTCHIna/TiO2 composite using box-behnken design application

Sustainable Chemistry for Climate Action Pub Date : 2024-09-18 DOI:10.1016/j.scca.2024.100047

Adawiah Adawiah , Soniah Fitriani , Leni Andriyani , Yulyani Nur Azizah , Wahyudin Wahyudin , Dede Sukandar , Agustino Zulys

{"title":"Optimization of methylene blue photodegradation by Cr-PTCHIna/TiO2 composite using box-behnken design application","authors":"Adawiah Adawiah , Soniah Fitriani , Leni Andriyani , Yulyani Nur Azizah , Wahyudin Wahyudin , Dede Sukandar , Agustino Zulys","doi":"10.1016/j.scca.2024.100047","DOIUrl":null,"url":null,"abstract":"<div><div>The Cr-PTC<img>HIna/TiO<sub>2</sub> composite synthesized using an isonicotinic acid modulated chromium and perylene-based metal-organic framework (Cr-PTC<img>HIna MOF) and titanium oxide (TiO<sub>2</sub>) showed promising results for the photodegradation of methylene blue. The composite was synthesized through the solvothermal method with a molar ratio of Cr and Ti of 1:1 mmol. The XRD diffraction patterns of Cr-PTC<img>HIna/TiO<sub>2</sub> composite showed sharp peaks at 2θ = 12°, 25°, 27°, 37°, 48°, 54°, 55°, and 62° with crystal sizes of 14.144 nm. The Cr-PTC<img>HIna/TiO<sub>2</sub> composite has a band gap energy of 2.02 eV and a rod-shaped morphology with a particle size of 239.16 nm. The Box-Behnken Design (BBD) demonstrated that the composite can achieve an optimum degradation efficiency of methylene blue of 88.55 % under methylene blue initial concentration of 35.7 ppm, pH 6.6, and photocatalyst mass of 0.13 % under 250-watt Mercury lamp irradiation for 2 h.</div></div>","PeriodicalId":101195,"journal":{"name":"Sustainable Chemistry for Climate Action","volume":"5 ","pages":"Article 100047"},"PeriodicalIF":0.0000,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Sustainable Chemistry for Climate Action","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2772826924000105","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

Abstract

The Cr-PTCHIna/TiO₂ composite synthesized using an isonicotinic acid modulated chromium and perylene-based metal-organic framework (Cr-PTCHIna MOF) and titanium oxide (TiO₂) showed promising results for the photodegradation of methylene blue. The composite was synthesized through the solvothermal method with a molar ratio of Cr and Ti of 1:1 mmol. The XRD diffraction patterns of Cr-PTCHIna/TiO₂ composite showed sharp peaks at 2θ = 12°, 25°, 27°, 37°, 48°, 54°, 55°, and 62° with crystal sizes of 14.144 nm. The Cr-PTCHIna/TiO₂ composite has a band gap energy of 2.02 eV and a rod-shaped morphology with a particle size of 239.16 nm. The Box-Behnken Design (BBD) demonstrated that the composite can achieve an optimum degradation efficiency of methylene blue of 88.55 % under methylene blue initial concentration of 35.7 ppm, pH 6.6, and photocatalyst mass of 0.13 % under 250-watt Mercury lamp irradiation for 2 h.

Abstract Image

查看原文本刊更多论文

应用箱式贝肯设计优化 Cr-PTCHIna/TiO2 复合材料对亚甲基蓝的光降解

利用异烟酸调制铬和过烯基金属有机框架（Cr-PTCHIna MOF）和氧化钛（TiO2）合成的 Cr-PTCHIna/TiO2 复合材料在亚甲基蓝的光降解方面显示出良好的效果。该复合材料是通过溶热法合成的，Cr 和 Ti 的摩尔比为 1:1 mmol。Cr-PTCHIna/TiO2 复合材料的 XRD 衍射图在 2θ = 12°、25°、27°、37°、48°、54°、55°和 62°处显示出尖锐的峰值，晶体尺寸为 14.144 nm。Cr-PTCHIna/TiO2 复合材料的带隙能为 2.02 eV，呈棒状形态，粒径为 239.16 nm。方框-贝肯设计（BBD）表明，在亚甲基蓝初始浓度为 35.7 ppm、pH 值为 6.6、光催化剂质量为 0.13 %、250 瓦汞灯照射 2 小时的条件下，该复合材料对亚甲基蓝的最佳降解效率可达 88.55 %。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Sustainable Chemistry for Climate Action

CiteScore

2.30

自引率

0.00%

发文量