A comprehensive investigation of the adsorption behaviour and mechanism of industrial waste sintering and bayer red muds for heavy metals.

Abstract

The issue of heavy metal pollution is a critical global concern that requires urgent solution. However, conventional heavy metal adsorbents are too costly to be applied in large-scale engineering. In this study, adsorption behavior and mechanism of sintering red mud (RM-A) and bayer red mud (RM-B) for heavy metals were investigated to address the disposal of red mud as industrial waste and remediation of heavy metal pollution. Batch adsorption experiments were conducted to explore the adsorption performances of RM-A and RM-B under various conditions. Characterization of RM-A and RM-B before and after adsorption by XRD, FTIR and SEM-EDX was applied to investigate the specific adsorption behavior and mechanism. Adsorption experiments of both RM-A and RM-B fitted pseudo-second-order kinetic model and Langmuir isotherm model, with estimated maximum adsorption capacity of 21.96 and 25.19 mg/g for Cd²⁺, 21.47 and 26.06 mg/g for Cu²⁺ and 55.47 and 59.65 mg/g for Pb²⁺, respectively. Precipitation transformation of calcite was the primary adsorption mechanism for RM-A, whereas ion exchange of cancrinite, surface coordination compounds of hematite and minor precipitation transformation of calcite accounted for the adsorption mechanism for RM-B. Overall, RM-A and RM-B exhibited best adsorption performance for Pb²⁺, with RM-B showing greater adsorption capacity attributed to its higher specific surface area. This study compared the adsorption properties of RM-A and RM-B for the first time and demonstrated that both red muds can be effectively applied to remove heavy metals, thereby contributing to the sustainable industrial waste management and resourceful reuse.