Zamaan Mukadam, Soren B Scott, Maria Magdalena Titirici, Ifan E L Stephens
{"title":"An alternative to petrochemicals: biomass electrovalorization.","authors":"Zamaan Mukadam, Soren B Scott, Maria Magdalena Titirici, Ifan E L Stephens","doi":"10.1098/rsta.2023.0262","DOIUrl":null,"url":null,"abstract":"<p><p>Replacing petrochemicals with refined waste biomass as a sustainable chemical source has become an attractive option to lower global carbon emissions. Popular methods of refining lignocellulosic waste biomass use thermochemical processes, which have significant environmental downsides. Using electrochemistry instead would overcome many of these downsides, directly driving chemical reactions with renewable electricity and revolutionizing the way many chemicals are produced today. This review mainly focuses on two furanic platform chemicals that are produced from the dehydration of cellulose, 5-hydroxymethylfurfural and furfural, which can be electrochemically reduced or oxidized to replace fuels and monomers that today are obtained from petrochemicals. Critical parameters such as electrode materials and electrolyte pH are discussed in relation to their influence on conversion efficiency and product distribution.This article is part of the discussion meeting issue 'Green carbon for the chemical industry of the future'.</p>","PeriodicalId":19879,"journal":{"name":"Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences","volume":"382 2282","pages":"20230262"},"PeriodicalIF":4.3000,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11448837/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences","FirstCategoryId":"103","ListUrlMain":"https://doi.org/10.1098/rsta.2023.0262","RegionNum":3,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/9/23 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"MULTIDISCIPLINARY SCIENCES","Score":null,"Total":0}
引用次数: 0
Abstract
Replacing petrochemicals with refined waste biomass as a sustainable chemical source has become an attractive option to lower global carbon emissions. Popular methods of refining lignocellulosic waste biomass use thermochemical processes, which have significant environmental downsides. Using electrochemistry instead would overcome many of these downsides, directly driving chemical reactions with renewable electricity and revolutionizing the way many chemicals are produced today. This review mainly focuses on two furanic platform chemicals that are produced from the dehydration of cellulose, 5-hydroxymethylfurfural and furfural, which can be electrochemically reduced or oxidized to replace fuels and monomers that today are obtained from petrochemicals. Critical parameters such as electrode materials and electrolyte pH are discussed in relation to their influence on conversion efficiency and product distribution.This article is part of the discussion meeting issue 'Green carbon for the chemical industry of the future'.
期刊介绍：
Continuing its long history of influential scientific publishing, Philosophical Transactions A publishes high-quality theme issues on topics of current importance and general interest within the physical, mathematical and engineering sciences, guest-edited by leading authorities and comprising new research, reviews and opinions from prominent researchers.
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