Hyo-Young Kim, Motonori Watanabe, Jun Tae Song, Miki Inada and Tatsumi Ishihara*,
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引用次数: 0
Abstract
Metal-supported protonic ceramic fuel cells were prepared, and the effects of a double columnar layer at the cathode side of BaZr0.44Ce0.36Y0.2O3 (BZCY) on power density and open-circuit voltage (OCV) were studied. The double columnar structure of Pr0.2Ce0.8O2 (PrDC) and BZCY was prepared with pulsed laser deposition. It was found that the insertion of the double columnar layer was highly effective for increasing the power density and OCV. The optimum composition of the double columnar was BZCY:PrDC = 7:3, with a thickness of 200 nm. The power density of PCFCs with the BZCY-PrDC double columnar reached 413 mW/cm2, and the OCV was approximately 1.05 V at 873 K, which is six times higher than that of a cell without a functional layer. The high power density of the cell was attributed to the decreased overpotential of the cathode. Therefore, the BZCY-PrDC double columnar layer is effective in expanding the reaction site by increasing the proton concentration at the cathodic interface.
期刊介绍:
ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.