Welding between rough copper foil and silica glass using green femtosecond laser

IF 5.4 3区 材料科学 Q2 CHEMISTRY, PHYSICAL
Jingyu Huo , Zirong Zeng , Jinhui Yuan , Minghuo Luo , Aiping Luo , Jiaming Li , Huan Yang , Nan Zhao , Qingmao Zhang
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Abstract

The assembly of glass and copper micro devices is widely applied in modern manufacturing industries. Laser welding is an efficient technique. However, weld defects and instability resulting from the low laser absorptivity of copper remain significant challenges. Surface roughness also poses a limitation for optical contact during welding preprocessing. In this work, femtosecond pulse and green light from the second harmonic generation were combined to increase the copper absorptivity. The silica glass and rough copper foil were effectively welded. Under the optimized parameters, a maximum shear strength of 17.19 MPa was obtained. The electron and lattice temperatures during the welding process were simulated using two-temperature model. The microscopical mechanism, element diffusion, and chemical reaction were investigated. A modified region in the glass was formed due to excessive laser energy and scattered subsequent laser pulses. Cu–O-Si bonds were detected on the welds. Welding stability at various temperatures was characterized, with shear strength maintained at approximately 12 MPa after thermal cycling from 0 to 100 °C and heating at 150 °C. This study demonstrated that effective and stable welding of silica glass and rough copper foil can be achieved using green femtosecond lasers.

使用绿色飞秒激光在粗糙铜箔和硅玻璃之间进行焊接
玻璃和铜微型设备的组装广泛应用于现代制造业。激光焊接是一种高效的技术。然而,由于铜对激光的吸收率较低,焊接缺陷和不稳定性仍然是重大挑战。表面粗糙度也限制了焊接预处理过程中的光学接触。在这项工作中,飞秒脉冲和二次谐波产生的绿光相结合,提高了铜的吸收率。硅玻璃和粗糙铜箔得到了有效焊接。在优化参数下,获得了 17.19 兆帕的最大剪切强度。利用双温模型模拟了焊接过程中的电子温度和晶格温度。研究了微观机理、元素扩散和化学反应。由于过高的激光能量和散射的后续激光脉冲,在玻璃中形成了一个改性区域。在焊缝上检测到了 Cu-O-Si 键。在不同温度下的焊接稳定性得到了表征,在 0 至 100 °C 的热循环和 150 °C 的加热过程中,剪切强度保持在约 12 MPa。这项研究表明,使用绿色飞秒激光可以实现硅玻璃和粗糙铜箔的有效、稳定焊接。
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来源期刊
ACS Applied Energy Materials
ACS Applied Energy Materials Materials Science-Materials Chemistry
CiteScore
10.30
自引率
6.20%
发文量
1368
期刊介绍: ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.
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