Thermal History and Fluid Regime during the Formation of the Eldjurta Biotite Granite Massif (Greater Caucasus): Reconstructions Based on Isotope (δ18O, δD) and Geochemical Data

IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS
E. O. Dubinina, A. S. Avdeenko, A. A. Nosova, Yu. N. Chizhova, S. E. Borisovskiy, O. M. Zhilicheva, A. Ya. Dokuchaev
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Abstract

Based on the geochemical and isotopic (δ18О, δD) data, the thermal and fluid conditions during the formation of the Eldjurta granite massif were reconstructed. Analysis of rocks collected from the core of the Tyrnyauz Superdeep Well (TSW) within the depth range of 1427–3923 m revealed their homogeneous isotopic parameters: the δ18O values of bulk samples, quartz, feldspars, and biotite in 12 samples of biotite granites are 8.50 ± 0.33, 9.55 ± 0.22, 8.40 ± 0.33 and 5.45 ± 0.40‰, respectively. The δD values in the biotite vary from −103.3 to −95.6‰. The closure temperatures of the oxygen isotope system of quartz are 440–980°C. The rock cooling history was reconstructed using a new approach based on the analysis of single quartz grains. This approach can be used for detailed reconstructions of thermal history during formation of intrusive bodies. The definite samples were used to demonstrate that Dodson’s equation is valid for description of the δ18O values of quartz in a granite system. The data obtained suggest that the studied part of the massif was formed in at least two almost simultaneous stages. The lower part of the massif was crystallized first, and the second injection of granite melt arrived immediately after the first portion has been crystallized, but had no yet had time to cool significantly. The Tc values in the lower part of the massif indicate the re-opening of the oxygen isotope system of quartz, with subsequent long-term isotope re-equilibration between minerals. This leads to decrease of the observed Tc values and the calculated cooling rates, which is related to increasing volume of the intrusive body and cooling within already heated rocks. Estimates of the isotopic parameters of the water component indicate the absence of exotic water fluid (meteoric or buried waters) during cooling of the massif. The variations of the δ18O values in the minerals of the Eldjurta biotite granites can be described in terms of a simple retrograde exchange at the cooling stage.

Abstract Image

Abstract Image

埃尔德尤尔塔生物花岗岩群(大高加索地区)形成过程中的热历史和流体制度:根据同位素(δ18O、δD)和地球化学数据进行重建
根据地球化学和同位素(δ18О、δD)数据,重建了埃尔德尤尔塔花岗岩群形成过程中的热和流体条件。对从 1427-3923 米深度范围内的 Tyrnyauz 超深井(TSW)岩心采集的岩石进行的分析表明,这些岩石具有同质同位素参数:在 12 个生物花岗岩样品中,大块样品、石英、长石和生物花岗岩的 δ18O 值分别为 8.50 ± 0.33、9.55 ± 0.22、8.40 ± 0.33 和 5.45 ± 0.40‰。黑云母的 δD 值在 -103.3 至 -95.6‰ 之间。石英氧同位素系统的闭合温度为 440-980°C。岩石冷却历史的重建采用了一种基于单个石英颗粒分析的新方法。这种方法可用于详细重建侵入体形成过程中的热历史。确定的样品被用来证明多德森方程对描述花岗岩体系中石英的 δ18O 值是有效的。所获得的数据表明,所研究的地块至少是在两个几乎同时的阶段形成的。地块的下部首先结晶,第二股花岗岩熔体在第一部分结晶后立即注入,但尚未来得及明显冷却。地块下部的 Tc 值表明石英的氧同位素系统重新开放,随后矿物之间进行了长期的同位素再平衡。这导致观测到的 Tc 值和计算出的冷却速率下降,这与侵入体体积增大和已加热岩石内部冷却有关。对水成分同位素参数的估计表明,在地块冷却过程中不存在外来水流体(陨石水或埋藏水)。埃尔德尤尔塔生物花岗岩矿物中 δ18O 值的变化可以用冷却阶段的简单逆向交换来描述。
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来源期刊
Petrology
Petrology 地学-地球科学综合
CiteScore
2.40
自引率
20.00%
发文量
27
审稿时长
>12 weeks
期刊介绍: Petrology is a journal of magmatic, metamorphic, and experimental petrology, mineralogy, and geochemistry. The journal offers comprehensive information on all multidisciplinary aspects of theoretical, experimental, and applied petrology. By giving special consideration to studies on the petrography of different regions of the former Soviet Union, Petrology provides readers with a unique opportunity to refine their understanding of the geology of the vast territory of the Eurasian continent. The journal welcomes manuscripts from all countries in the English or Russian language.
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