Oxidation behaviors of yttrium silicate modified SiCf/SiC composites in air and water-oxygen environments

IF 3.5 3区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS
Fang He, Yejie Cao, Yongsheng Liu, Jingxin Li, Jing Wang, Binghui Zhang, Ning Dong
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Abstract

SiCf/SiC composites have emerged as one of the most promising materials for aero-engine hot-end structures. However, their performance is limited by their susceptibility to oxidation and corrosion reactions with oxygen and water vapor. To overcome this challenge, antioxidant-modified phases are introduced into matrices of SiCf/SiC composites which improve their water and oxygen resistance. In this study, the resistance of SiCf/SiC composites modified by yttrium silicate matrix (SiCf/SiC-YS composites) to air at 1000–1400°C and water-oxygen environments at 1200°C was investigated. The diffusion paths of oxygen in SiCf/SiC-YS composites and the antioxidant behavior of the yttrium silicate matrix were discussed. Additionally, the differences in oxygen and water-oxygen corrosion resistance of SiCf/SiC-YS composites at the same temperature were compared. The strength retention of SiCf/SiC-YS composites after oxidation and water-oxygen corrosion at 1200°C were 138.6% and 108.8%, respectively. This indicates that the addition of water vapor accelerated the degradation of SiCf/SiC-YS composites. By comparing with SiCf/SiC composites, it can be concluded that the modification of the yttrium silicate matrix considerably improved the oxidation resistance of SiCf/SiC composites.

硅酸钇改性碳化硅/碳化硅复合材料在空气和水氧环境中的氧化行为
碳化硅/碳化硅复合材料已成为最有前途的航空发动机热端结构材料之一。然而,由于易与氧气和水蒸气发生氧化和腐蚀反应,其性能受到了限制。为了克服这一难题,人们在碳化硅/碳化硅复合材料的基体中引入了抗氧化剂改性相,以提高其耐水和耐氧性。在本研究中,研究了硅酸钇基体改性的 SiCf/SiC 复合材料(SiCf/SiC-YS 复合材料)在 1000-1400°C 的空气环境和 1200°C 的水氧环境中的耐受性。讨论了氧在 SiCf/SiC-YS 复合材料中的扩散路径以及硅酸钇基体的抗氧化行为。此外,还比较了 SiCf/SiC-YS 复合材料在相同温度下的抗氧腐蚀性和抗水氧腐蚀性的差异。SiCf/SiC-YS 复合材料在 1200°C 氧化和水氧腐蚀后的强度保持率分别为 138.6% 和 108.8%。这表明水蒸气的加入加速了 SiCf/SiC-YS 复合材料的降解。通过与 SiCf/SiC 复合材料的比较,可以得出结论:硅酸钇基体的改性大大提高了 SiCf/SiC 复合材料的抗氧化性。
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来源期刊
Journal of the American Ceramic Society
Journal of the American Ceramic Society 工程技术-材料科学:硅酸盐
CiteScore
7.50
自引率
7.70%
发文量
590
审稿时长
2.1 months
期刊介绍: The Journal of the American Ceramic Society contains records of original research that provide insight into or describe the science of ceramic and glass materials and composites based on ceramics and glasses. These papers include reports on discovery, characterization, and analysis of new inorganic, non-metallic materials; synthesis methods; phase relationships; processing approaches; microstructure-property relationships; and functionalities. Of great interest are works that support understanding founded on fundamental principles using experimental, theoretical, or computational methods or combinations of those approaches. All the published papers must be of enduring value and relevant to the science of ceramics and glasses or composites based on those materials. Papers on fundamental ceramic and glass science are welcome including those in the following areas: Enabling materials for grand challenges[...] Materials design, selection, synthesis and processing methods[...] Characterization of compositions, structures, defects, and properties along with new methods [...] Mechanisms, Theory, Modeling, and Simulation[...] JACerS accepts submissions of full-length Articles reporting original research, in-depth Feature Articles, Reviews of the state-of-the-art with compelling analysis, and Rapid Communications which are short papers with sufficient novelty or impact to justify swift publication.
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