Pengcheng Dou , Guangyu He , Yinghong Li , Zhaolu Zhang , Yan Chai
{"title":"Thermo-mechanical coupling effect induced morphology evolution in laser stripping anti-erosion TiN coatings","authors":"Pengcheng Dou , Guangyu He , Yinghong Li , Zhaolu Zhang , Yan Chai","doi":"10.1016/j.optlastec.2024.111817","DOIUrl":null,"url":null,"abstract":"<div><p>Laser stripping has emerged as a pivotal technique for repairing anti-erosion coatings in the aviation and armored vehicle industries. This process entails complex thermodynamic interactions that remain incompletely explored. Unraveling the intricacies of the stripping mechanism, especially the evolution of surface morphology, is essential for advancing its industrial utility. This study characterizes the laser stripping effect on TiN anti-erosion coatings using confocal microscopy, scanning electron microscopy, and energy dispersive spectrometer. Notably, at an energy density threshold of approximately 10<sup>2</sup> J/cm<sup>2</sup>, pulsed lasers are observed to induce a distinctive hydrodynamic surface morphology, marked by parallel asymmetric grooves. This phenomenon is accompanied by a redistribution of surface elements and a decrease in nitrogen content. To dissect the underlying mechanisms, we have developed simulation models that integrate principles of heat transfer and fluid dynamics. These models reveal that the high-temperature decomposition and vaporization of TiN, coupled with the ejection of molten material due to vapor recoil pressure, are central to the stripping process. Additionally, the formation of asymmetric groove profiles is predominantly attributed to the nonlinear superposition effect from overlapping laser spots.</p></div>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":null,"pages":null},"PeriodicalIF":5.4000,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Energy Materials","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0030399224012751","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Laser stripping has emerged as a pivotal technique for repairing anti-erosion coatings in the aviation and armored vehicle industries. This process entails complex thermodynamic interactions that remain incompletely explored. Unraveling the intricacies of the stripping mechanism, especially the evolution of surface morphology, is essential for advancing its industrial utility. This study characterizes the laser stripping effect on TiN anti-erosion coatings using confocal microscopy, scanning electron microscopy, and energy dispersive spectrometer. Notably, at an energy density threshold of approximately 102 J/cm2, pulsed lasers are observed to induce a distinctive hydrodynamic surface morphology, marked by parallel asymmetric grooves. This phenomenon is accompanied by a redistribution of surface elements and a decrease in nitrogen content. To dissect the underlying mechanisms, we have developed simulation models that integrate principles of heat transfer and fluid dynamics. These models reveal that the high-temperature decomposition and vaporization of TiN, coupled with the ejection of molten material due to vapor recoil pressure, are central to the stripping process. Additionally, the formation of asymmetric groove profiles is predominantly attributed to the nonlinear superposition effect from overlapping laser spots.
期刊介绍:
ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.