Manufacturing High Strength-Toughness High-Nitrogen Stainless Bearing Steel 30Cr15Mo1VN by Pressurized Duplex Process

Ling-Feng Xia, Hao Feng, Hua-Bing Li, Shu-Cai Zhang, Hong-Chun Zhu, Zhou-Hua Jiang
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Abstract

The high-nitrogen stainless bearing steel 30Cr15Mo1VN, possessing excellent tensile strength (~ 2466 MPa) and impact toughness (~ 130.3 J), was manufactured by pressurized induction melting and pressurized electroslag remelting (PIM + PESR) duplex process. Herein, the inclusion characteristics and element segregation of as-cast ingots, as well as the precipitate characteristics, retained austenite (RA) distribution were systematically investigated to clarify the effect of PESR on tensile and impact properties. Compared with PIM ingot, the lower quantity and larger spacing of inclusions in PIM + PESR ingot were beneficial to improving toughness. Besides, the dendrite segregation originating from solidification inherited to tempered steels and changed the multiphase structure and toughening mechanism. First, the lighter segregation (C, N, Cr, etc.) was induced by the high cooling rate, directional solidification, and short-time homogenization during PESR process, obtaining the higher contents of precipitates and RA in the PIM + PESR ingot. Second, the smaller precipitates and more RA were uniformly distributed in tempered PIM + PESR steel by alleviating segregation, obtaining better interface and matrix plasticity. Third, the dislocation densities of martensite and RA were increased by the greater precipitation pinning effect after PESR, and the uniform area ratios of close-packed and Bain groups were obtained, effectively inhibiting the propagation of secondary crack. Finally, the smaller strength difference between RA and martensite owing to lighter segregation after PESR, alleviated strain localization at phase interfaces and accommodated plastic deformation of matrix, thus, significantly enhancing the strength and toughness of the PIM+PESR steel.

Abstract Image

通过加压双相工艺制造高强度-高韧性-高氮不锈钢轴承钢 30Cr15Mo1VN
采用加压感应熔炼和加压电渣重熔(PIM + PESR)双相工艺生产了具有优异抗拉强度(~ 2466 MPa)和冲击韧性(~ 130.3 J)的高氮不锈钢轴承钢 30Cr15Mo1VN。本文系统研究了铸锭的夹杂特性和元素偏析,以及析出物特性和残余奥氏体(RA)分布,以阐明 PESR 对拉伸和冲击性能的影响。与 PIM 钢锭相比,PIM + PESR 钢锭中夹杂物的数量更少、间距更大,有利于提高韧性。此外,凝固过程中产生的树枝晶偏析继承到回火钢中,改变了多相结构和增韧机理。首先,PESR 过程中的高冷却速率、定向凝固和短时间均化诱发了较轻的偏析(C、N、Cr 等),从而在 PIM + PESR 钢锭中获得了较高的析出物和 RA 含量。其次,PIM + PESR 回火钢中析出物较小,RA 含量较高,通过缓解偏析均匀分布,获得了较好的界面塑性和基体塑性。第三,PESR 后更大的析出针化效应提高了马氏体和 RA 的位错密度,获得了均匀的紧密堆积和贝恩基团面积比,有效抑制了二次裂纹的扩展。最后,由于 PESR 后偏析较轻,RA 和马氏体之间的强度差异较小,从而缓解了相界面的应变局部化,容纳了基体的塑性变形,从而显著提高了 PIM+PESR 钢的强度和韧性。
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