Synthesis of Trimanganese Tetraoxide (Mn3O4) as a promising electrode and Photocatalyst for the degradation of Rhodamine B dye

Abstract

The article involves the facile bio-synthesis of Manganese (III) Oxide (Mn₃O₄) nanoparticles (NPs) using Curry leaf (Murraya Koenigii) extract as an efficacious chelating agent. The prepared NPs were subjected to various characterization methods such as Powder X-ray diffraction (XRD), Scanning Electron Microscopy (SEM) with Energy Dispersive X-Ray (EDX) Analysis, Transmission Electron Microscopy (TEM), Fourier Transform Infrared analysis (FTIR), Ultra Violet spectroscopy study (UV–Vis), Cyclic Voltammetry (CV) and Vibrating Sample Magnetometer (VSM) to study the crystalline structure, morphology, optical properties, electrochemical activity and magnetic property of the sample. The XRD result proved the crystallinity of the sample having crystallite size around 15 nm with tetragonal structure. The absorption band observed at 612 cm⁻¹ indicates the Mn-O stretching modes of tetrahedral sites in FTIR analysis of the prepared sample which confirmed the formation of Mn₃O₄ NPs. Using SEM and TEM techniques, the surface morphology and NPs size were examined. The composition and distribution of the NPs was verified using EDX spectrum and elemental mapping. Using the UV–Visible spectroscopy, the energy band gap (Eg) for the NPs was computed and calculated as 2.34 eV. The Mn₃O₄ NPs evinced a specific capacitance of 276 Fg^-1 at 10 mV/s scan rate. This result proposes that the obtained Mn₃O₄ NPs can be used as a suitable electrode mainly for supercapacitor applications. VSM study revealed the paramagnetic behavior of the synthesized Mn₃O₄ NPs. The synthesized Mn₃O₄ NPs exhibited moderate antibacterial activity with gram positive bacteria such as Staphylococcus aureus, Streptococcus pneumoniae, and gram negative bacteria such as Klebsiella pneumoniae, with the inhibition zones of 12, 10, and 9 mm respectively. Photo catalytic degradation study was carried out for Rhodamine B (RhB) dye, which showed a strong characteristic absorption peak nearly at 554 nm with 94 % of degradation efficiency.