A flower-like g-C3N4/CDs/Bi2WO6 hierarchical structure for enhanced photocatalytic degradation of tetracycline

Abstract

Tetracycline (TC), as one of antibiotic emerging pollutants, has posed potential threats to ecological environment and human health because it is hardly biodegradable and prone to be accumulated in water. In this study, g-C₃N₄/CDs/Bi₂WO₆ S-scheme heterojunction with flower-like hierarchical structure was synthesized by hydrothermal method. The optimized composite demonstrates significantly enhanced photocatalytic activity with a TC degradation efficiency of 90.1% after 120 min of visible light irradiation and good reusability up to four consecutive cycles. This can be attributed to the improved light capture capability and efficient separation of photo-generated electron-hole pairs in the constructed S-scheme heterojunction. The introduced carbon dots (CDs) can be served as an efficient carrier transport highway, providing a superior photogenerated carrier separation efficiency and an expanded absorption spectrum. As a result, the strongest redox potentials of the CB_CN and VB_BWO can be retained for participating the photocatalytic reaction. Free radical capture and electron spin resonance experiments indicate that ·O₂^- and h⁺ are the principal active species in the g-C₃N₄/CDs/Bi₂WO₆ system. This work provides new strategy for the development of advanced materials in the field of photocatalytic treatment of wastewater.