New Heteroligand Octahedral Cluster Complexes of Molybdenum and Tungsten

IF 1.2 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Structural Chemistry Pub Date : 2024-09-04 DOI:10.1134/S0022476624080043

A. S. Pronin, T. S. Sukhikh, Y. V. Mironov

引用次数: 0

Abstract

The (Bu₄N)₂[{Mo₆I₈}(CN)₅(OEt)]·2H₂O and (Bu₄N)₂[{W₆I₈}(CN)₄(OEt)₂]·H₂O·EtOH cluster complexes are prepared by the reaction of (Bu₄N)₂[{M₆I₈}I₆] (M = Mo, W) with NaCN in ethanol and subsequent recrystallization from an aqueous ethanol solution. The structure of both compounds is determined by XRD. The external ligand environment of the anions contains CN^– and OEt^– ligands. The behavior of the complexes in an aqueous solution is studied by electron spectroscopy.

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钼和钨的新型异配位体八面体簇合物

摘要 (Bu4N)2[{Mo6I8}(CN)5(OEt)]-2H2O和(Bu4N)2[{W6I8}(CN)4(OEt)2]-H2O-EtOH簇合物是由(Bu4N)2[{M6I8}I6]（M = Mo，W）与 NaCN 在乙醇中反应，然后从乙醇水溶液中重结晶制备的。这两种化合物的结构都是通过 XRD 确定的。阴离子的外部配体环境包含 CN- 和 OEt- 配体。电子光谱法研究了这些配合物在水溶液中的行为。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Structural Chemistry 化学-无机化学与核化学

CiteScore

1.60

自引率

12.50%

发文量

142

审稿时长

8.3 months

期刊介绍： Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.