Writing with Mass-Selected Ions Using a Dynamic Field Wien Filter

IF 3.1 2区 化学 Q2 BIOCHEMICAL RESEARCH METHODS
Michael F. Espenship, Julia Laskin
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引用次数: 0

Abstract

We have designed and constructed a low-cost Wien filter based on strong permanent magnets and integrated it into an ion soft-landing instrument to enable parallel deposition as well as one- and two-dimensional surface patterning of mass-selected ions using dynamic fields. We show the capabilities of this device for separating ions from a multicomponent high-flux continuous ion beam and simultaneous deposition of ions of different mass-to-charge ratios onto discrete locations on a surface. When a dynamic electric field is applied parallel to the magnetic field, ions are deposited in one-dimensional arrays, laterally separated by mass. The field’s strength, frequency, and waveform type determine both the lengths of the arrays and the density of ions across the 1-D pattern. Additionally, a second dynamic field from user-defined waveforms orthogonal to the magnetic field enables two-dimensional surface patterning of ions while maintaining mass separation. These experiments demonstrate the practical utility of a Wien filter for the controlled fabrication of interfaces with arbitrary patterns of mass-selected ions.

Abstract Image

使用动态场维恩滤波器写入质量选择离子
我们设计并建造了一种基于强永磁体的低成本维恩滤波器,并将其集成到离子软着陆仪器中,从而利用动态场实现质量选择离子的平行沉积以及一维和二维表面图案化。我们展示了该设备从多组分高通量连续离子束中分离离子并同时将不同质量电荷比的离子沉积到表面离散位置的能力。当施加与磁场平行的动态电场时,离子沉积成一维阵列,按质量横向分开。电场的强度、频率和波形类型决定了阵列的长度和一维图案上的离子密度。此外,由用户定义的与磁场正交的波形产生的第二个动态磁场可在保持质量分离的同时对离子进行二维表面图案化。这些实验证明了维恩滤波器在控制制造具有任意质量选择离子图案的界面方面的实用性。
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来源期刊
CiteScore
5.50
自引率
9.40%
发文量
257
审稿时长
1 months
期刊介绍: The Journal of the American Society for Mass Spectrometry presents research papers covering all aspects of mass spectrometry, incorporating coverage of fields of scientific inquiry in which mass spectrometry can play a role. Comprehensive in scope, the journal publishes papers on both fundamentals and applications of mass spectrometry. Fundamental subjects include instrumentation principles, design, and demonstration, structures and chemical properties of gas-phase ions, studies of thermodynamic properties, ion spectroscopy, chemical kinetics, mechanisms of ionization, theories of ion fragmentation, cluster ions, and potential energy surfaces. In addition to full papers, the journal offers Communications, Application Notes, and Accounts and Perspectives
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