Broadband multiple resonant metasurface for mixture surface-enhanced infrared absorption based on polarization-sensitive folded nanoantennas

Abstract

Multiple resonant metasurfaces for mixture component detection by surface-enhanced infrared absorption in a broadband spectrum region are still highly desirable. This paper presents a polarization-sensitive multi-resonant broadband metasurface in the mid-infrared (MIR) region based on an odd symmetric folded antenna array. Six major resonant modes are effectively excited in 6–15 μm covering the absorption peak of multiple gases and biomolecules. In addition, the calculation indicates the maximum electric field intensity enhancement reaches 3607 and the average electric enhancement factors are dominantly amplified to a maximum of 75.08. The excited multiple hotspots provide more spatial overlap with analytes and would be beneficial for label-free detection. Moreover, owing to the contributions of the intrinsic phonons and polaritons in the ENZ material, the spectroscopy features are relatively stable when changing the geometry parameters and the incident angles, allowing more fabrication tolerance and experiment flexibility. Furthermore, the multiple resonant metasurface is also effectively enabled under orthogonal circular polarizations. Finally, the sensing abilities of the designed metasurface for polyethylene terephthalate and isopropanol molecules have been computationally validated. These results indicate the potential for nanophotonic detection and mixture spectroscopy analysis.