Rapidly synthesis of AuM (M = Pt, Pd) hexagonals/graphene quantum dots nanostructures and their application for non-enzyme hydrogen peroxide detection

IF 2.7 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
Tran Thi Bich Quyen, Ngo Nguyen Tra My, Nguyen Thi Quyen Tran, Tran Minh Khang, Luong Huynh Vu Thanh, Bui Le Anh Tuan, Duy Toan Pham, Nguyen Le Thanh Huynh
{"title":"Rapidly synthesis of AuM (M = Pt, Pd) hexagonals/graphene quantum dots nanostructures and their application for non-enzyme hydrogen peroxide detection","authors":"Tran Thi Bich Quyen, Ngo Nguyen Tra My, Nguyen Thi Quyen Tran, Tran Minh Khang, Luong Huynh Vu Thanh, Bui Le Anh Tuan, Duy Toan Pham, Nguyen Le Thanh Huynh","doi":"10.1557/s43578-024-01435-0","DOIUrl":null,"url":null,"abstract":"<p>In this study, AuM (M = Pt, Pd) bimetallic hexagonals (AuM BHGs) were successfully combined with graphene quantum dots (GQDs) by a simple method at ambient temperature (~ 30 °C) to form AuM BHGs/GQDs nanocomposites with enhanced properties and electro-activities. The synthesized AuM BHGs/GQDs were also characterized by UV–Vis, XRD, FTIR, XPS, AFM, TEM, and EDS. The novel AuM BHGs/GQDs were successfully synthesized, possessed an average particle size of AuM BHGs (~ 50–60 nm) and GQDs (~ 6–16 nm), and were homogeneously distributed in the dispersion. Furthermore, AuM BHGs/GQDs nanocomposites were also investigated as a sensitive sensor in the H<sub>2</sub>O<sub>2</sub> detection by cyclic voltammetry method, with a low H<sub>2</sub>O<sub>2</sub> limit of detection (LOD) of 0.865 nM, high sensitivity of 1.27 μAnM<sup>−1</sup>cm<sup>−2</sup> and a wide detection range from 10<sup>–12</sup> to 10<sup>–3</sup> M. Therefore, AuM BHG/GQDs nanocomposites could be used to detect H<sub>2</sub>O<sub>2</sub> with high sensitivity and fast response.</p><h3 data-test=\"abstract-sub-heading\">Graphical abstract</h3>","PeriodicalId":16306,"journal":{"name":"Journal of Materials Research","volume":"6 1","pages":""},"PeriodicalIF":2.7000,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Research","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1557/s43578-024-01435-0","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

In this study, AuM (M = Pt, Pd) bimetallic hexagonals (AuM BHGs) were successfully combined with graphene quantum dots (GQDs) by a simple method at ambient temperature (~ 30 °C) to form AuM BHGs/GQDs nanocomposites with enhanced properties and electro-activities. The synthesized AuM BHGs/GQDs were also characterized by UV–Vis, XRD, FTIR, XPS, AFM, TEM, and EDS. The novel AuM BHGs/GQDs were successfully synthesized, possessed an average particle size of AuM BHGs (~ 50–60 nm) and GQDs (~ 6–16 nm), and were homogeneously distributed in the dispersion. Furthermore, AuM BHGs/GQDs nanocomposites were also investigated as a sensitive sensor in the H2O2 detection by cyclic voltammetry method, with a low H2O2 limit of detection (LOD) of 0.865 nM, high sensitivity of 1.27 μAnM−1cm−2 and a wide detection range from 10–12 to 10–3 M. Therefore, AuM BHG/GQDs nanocomposites could be used to detect H2O2 with high sensitivity and fast response.

Graphical abstract

Abstract Image

快速合成 AuM(M = Pt、Pd)六边形/石墨烯量子点纳米结构及其在非酶过氧化氢检测中的应用
本研究采用一种简单的方法,在环境温度(~ 30 °C)下成功地将 AuM(M = Pt、Pd)双金属六边形(AuM BHGs)与石墨烯量子点(GQDs)结合在一起,形成了具有增强性能和电活性的 AuM BHGs/GQDs 纳米复合材料。合成的 AuM BHGs/GQDs 还通过 UV-Vis、XRD、FTIR、XPS、AFM、TEM 和 EDS 进行了表征。成功合成的新型 AuM BHGs/GQDs 具有 AuM BHGs(约 50-60 nm)和 GQDs(约 6-16 nm)的平均粒径,并在分散体中均匀分布。因此,AuM BHG/GQDs 纳米复合材料可用于高灵敏度和快速响应的 H2O2 检测。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Journal of Materials Research
Journal of Materials Research 工程技术-材料科学:综合
CiteScore
4.50
自引率
3.70%
发文量
362
审稿时长
2.8 months
期刊介绍: Journal of Materials Research (JMR) publishes the latest advances about the creation of new materials and materials with novel functionalities, fundamental understanding of processes that control the response of materials, and development of materials with significant performance improvements relative to state of the art materials. JMR welcomes papers that highlight novel processing techniques, the application and development of new analytical tools, and interpretation of fundamental materials science to achieve enhanced materials properties and uses. Materials research papers in the following topical areas are welcome. • Novel materials discovery • Electronic, photonic and magnetic materials • Energy Conversion and storage materials • New thermal and structural materials • Soft materials • Biomaterials and related topics • Nanoscale science and technology • Advances in materials characterization methods and techniques • Computational materials science, modeling and theory
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信