Fabrication and Properties of Superhydrophobic Colored Stainless Steel Surface for Decoration and Anti-Corrosion

Abstract

A colored superhydrophobic surface on a stainless steel substrate was achieved by means of high temperature oxidation combined with subsequent spraying modification by superhydrophobic nano-silica film. Comprehensive characterizations of the surface were performed in terms of color, morphology, composition, wettability, and corrosion resistance by optical microscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), contact angle, potentiodynamic polarization, and electrochemical impedance spectroscopy measurement. At 400 °C, the surface was pale yellow, gradually turning yellow and then red as the temperature increased. At 700 °C and 800 °C, the surface colors were blue and dark brown, respectively. The samples with oxide films demonstrated lower contact angles, specifically 80.5° ± 2.5 at 400 °C, 79.1° ± 2.8 at 500 °C, and 75.6° ± 3.4 at 600 °C. The polarization resistance measured on the oxidized film formed at 600 °C exceeded 7.93 × 104 Ω·cm2. After spraying the treatment, these colorful surfaces exhibited superhydrophobicity, they were self-cleaning, and they satisfied anti-corrosion properties. The treatment performs as an excellent barrier and exhibits a high corrosion resistance of 4.68 × 106 Ω·cm2. The successful preparation of superhydrophobic colored surfaces offers the possibility of providing stainless steel with both decoration value and self-cleaning function simultaneously by our proposed chromium-free fabrication process.