Synthesis and Crystal Structures of Ferrocenylamine Alcohols of Ferrocenylformaldehyde with Aminoalcohols

IF 0.4 4区化学 Q4 CRYSTALLOGRAPHY

Journal of Chemical Crystallography Pub Date : 2024-08-30 DOI:10.1007/s10870-024-01029-y

Dan-Dan Lu, Ya-Meng Zhu, Yi-Jie Li, Ai-Quan Jia, Qian-Feng Zhang

引用次数: 0

Abstract

Two chiral ferrocenylamine alcohols of (R)-[Fe(η⁵-C₅H₅){η⁵-C₅H₄CH₂NHCH(ⁱPr)(CH₂OH)}] (1) and (R)-[Fe(η⁵-C₅H₅){η⁵-C₅H₄CH₂NHCH(C₆H₅)(CH₂OH)}] (2) were synthesized by condensation reaction of ferrocenylformaldehyde and chiral aminoalcohols followed by the reduction with sodium borohydride. The crystal structures of the two compounds were determined by single crystal X-ray diffraction. Compound 1 crystallizes in the orthorhombic space group P2₁2₁2 with a = 16.600(8) Å, b = 28.990(14) Å, c = 6.531(3) Å, and Z = 8. Compound 21.13H₂O crystallizes in the monoclinic space group I2 with a = 22.671(4) Å, b = 6.2481(10) Å, c = 22.112(4) Å, β = 96.763(12)°, and Z = 8.

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二茂铁基甲醛的二茂铁基胺醇与氨基醇的合成及其晶体结构

(R)-[Fe(η5-C5H5){η5-C5H4CH2NHCH(iPr)(CH2OH)}] (1) 和 (R)-[Fe(η5-C5H5){η5-C5H4CH2NHCH(C6H5)(CH2OH)}](2)是通过二茂铁甲醛和手性氨基醇的缩合反应，然后用硼氢化钠还原合成的。通过单晶 X 射线衍射测定了这两种化合物的晶体结构。化合物 1 在正交空间群 P21212 中结晶，a = 16.600(8) Å，b = 28.990(14) Å，c = 6.531(3) Å，Z = 8。化合物 21.13H2O 在单斜空间群 I2 中结晶，a = 22.671(4)埃，b = 6.2481(10)埃，c = 22.112(4)埃，β = 96.763(12)°，Z = 8。

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来源期刊

Journal of Chemical Crystallography 化学-光谱学

CiteScore

1.50

自引率

12.50%

发文量

审稿时长

6.3 months

期刊介绍： Journal of Chemical Crystallography is an international and interdisciplinary publication dedicated to the rapid dissemination of research results in the general areas of crystallography and spectroscopy. Timely research reports detail topics in crystal chemistry and physics and their relation to problems of molecular structure; structural studies of solids, liquids, gases, and solutions involving spectroscopic, spectrometric, X-ray, and electron and neutron diffraction; and theoretical studies.