Experimental Study of the Ignition of a Stoichiometric Propylene–Oxygen–Argon Mixture Behind a Reflected Shock Wave

IF 1.4 4区 化学 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL
P. V. Kozlov, M. A. Kotov, G. Ya. Gerasimov, V. Yu. Levashov, N. G. Bykova, I. E. Zabelinskii
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引用次数: 0

Abstract

The self-ignition of a propylene–oxygen–argon stoichiometric mixture with a volumetric argon content of 95% is studied. The experiments are performed on a shock tube, which is part of the Shock Tube Experimental Complex of the Institute of Mechanics of Moscow State University, in conditions behind the reflected shock wave. The time dependencies of signals from a piezoelectric pressure sensor, a thermoelectric detector, and an optical section configured to record the radiation of electronically excited radicals OH (λ = 302 nm), CH (λ = 427 nm, and molecular carbon \({\text{C}}_{2}^{\centerdot }\) (λ = 553 nm) are analyzed. The ignition delay times τign are measured in the temperature range T = 1200–2460 K and pressures p = 4.5–25 atm. The data obtained are compared with the results of other authors.

Abstract Image

Abstract Image

关于在反射冲击波后点燃定量丙烯-氧气-氩气混合物的实验研究
摘要 研究了体积氩含量为 95% 的丙烯-氧气-氩气化学计量混合物的自燃问题。实验是在反射冲击波后的条件下,在莫斯科国立大学力学研究所冲击管实验综合体的冲击管上进行的。实验分析了来自压电压力传感器、热电探测器和光学部分的信号的时间相关性,这些部分被配置为记录电子激发自由基 OH- (λ = 302 nm)、CH- (λ = 427 nm) 和分子碳 \({\text{C}}_{2}^\{centerdot }\) (λ = 553 nm)的辐射。在温度范围 T = 1200-2460 K 和压力 p = 4.5-25 atm 的条件下测量了点火延迟时间 τign。获得的数据与其他作者的结果进行了比较。
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来源期刊
Russian Journal of Physical Chemistry B
Russian Journal of Physical Chemistry B 化学-物理:原子、分子和化学物理
CiteScore
2.20
自引率
71.40%
发文量
106
审稿时长
4-8 weeks
期刊介绍: Russian Journal of Physical Chemistry B: Focus on Physics is a journal that publishes studies in the following areas: elementary physical and chemical processes; structure of chemical compounds, reactivity, effect of external field and environment on chemical transformations; molecular dynamics and molecular organization; dynamics and kinetics of photoand radiation-induced processes; mechanism of chemical reactions in gas and condensed phases and at interfaces; chain and thermal processes of ignition, combustion and detonation in gases, two-phase and condensed systems; shock waves; new physical methods of examining chemical reactions; and biological processes in chemical physics.
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