P. V. Kozlov, M. A. Kotov, G. Ya. Gerasimov, V. Yu. Levashov, N. G. Bykova, I. E. Zabelinskii
{"title":"Experimental Study of the Ignition of a Stoichiometric Propylene–Oxygen–Argon Mixture Behind a Reflected Shock Wave","authors":"P. V. Kozlov, M. A. Kotov, G. Ya. Gerasimov, V. Yu. Levashov, N. G. Bykova, I. E. Zabelinskii","doi":"10.1134/S1990793124700568","DOIUrl":null,"url":null,"abstract":"<p>The self-ignition of a propylene–oxygen–argon stoichiometric mixture with a volumetric argon content of 95% is studied. The experiments are performed on a shock tube, which is part of the Shock Tube Experimental Complex of the Institute of Mechanics of Moscow State University, in conditions behind the reflected shock wave. The time dependencies of signals from a piezoelectric pressure sensor, a thermoelectric detector, and an optical section configured to record the radiation of electronically excited radicals OH<sup>•</sup> (λ = 302 nm), CH<sup>•</sup> (λ = 427 nm, and molecular carbon <span>\\({\\text{C}}_{2}^{\\centerdot }\\)</span> (λ = 553 nm) are analyzed. The ignition delay times τ<sub><i>ign</i></sub> are measured in the temperature range <i>T</i> = 1200–2460 K and pressures <i>p</i> = 4.5–25 atm. The data obtained are compared with the results of other authors.</p>","PeriodicalId":768,"journal":{"name":"Russian Journal of Physical Chemistry B","volume":null,"pages":null},"PeriodicalIF":1.4000,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry B","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1990793124700568","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The self-ignition of a propylene–oxygen–argon stoichiometric mixture with a volumetric argon content of 95% is studied. The experiments are performed on a shock tube, which is part of the Shock Tube Experimental Complex of the Institute of Mechanics of Moscow State University, in conditions behind the reflected shock wave. The time dependencies of signals from a piezoelectric pressure sensor, a thermoelectric detector, and an optical section configured to record the radiation of electronically excited radicals OH• (λ = 302 nm), CH• (λ = 427 nm, and molecular carbon \({\text{C}}_{2}^{\centerdot }\) (λ = 553 nm) are analyzed. The ignition delay times τign are measured in the temperature range T = 1200–2460 K and pressures p = 4.5–25 atm. The data obtained are compared with the results of other authors.
期刊介绍:
Russian Journal of Physical Chemistry B: Focus on Physics is a journal that publishes studies in the following areas: elementary physical and chemical processes; structure of chemical compounds, reactivity, effect of external field and environment on chemical transformations; molecular dynamics and molecular organization; dynamics and kinetics of photoand radiation-induced processes; mechanism of chemical reactions in gas and condensed phases and at interfaces; chain and thermal processes of ignition, combustion and detonation in gases, two-phase and condensed systems; shock waves; new physical methods of examining chemical reactions; and biological processes in chemical physics.