Chapter VI. Specificities of Hydrazine Ignition and Explosion as an Example of Anomalous Critical Phenomena

IF 1.3 4区化学 Q4 CHEMISTRY, PHYSICAL

Kinetics and Catalysis Pub Date : 2024-08-20 DOI:10.1134/S002315842460130X

V. V. Azatyan

引用次数: 0

Abstract

Based on the theory of nonisothermal chain reactions developed in the studies presented in the previous chapters, an experimentally verified explanation is given for the anomalous behavior of pyrolysis and combustion of a technically important product—hydrazine. The revealed kinetic features of N₂H₃ radicals, which led to the unusual properties of the hydrazine-oxygen ignition peninsula, are also explained. The mechanism of easy ignition and explosion has been clarified.

Abstract Image

查看原文本刊更多论文

第 VI 章.作为异常临界现象实例的肼点燃和爆炸的特殊性

摘要根据前几章研究中提出的非等温链式反应理论，对一种重要技术产品--肼的热解和燃烧的反常行为给出了经实验验证的解释。此外，还解释了 N2H3 自由基的动力学特征，这些特征导致了肼氧点火半岛的不寻常特性。易点燃和爆炸的机理也得到了澄清。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Kinetics and Catalysis 化学-物理化学

CiteScore

2.10

自引率

27.30%

发文量

审稿时长

6-12 weeks

期刊介绍： Kinetics and Catalysis Russian is a periodical that publishes theoretical and experimental works on homogeneous and heterogeneous kinetics and catalysis. Other topics include the mechanism and kinetics of noncatalytic processes in gaseous, liquid, and solid phases, quantum chemical calculations in kinetics and catalysis, methods of studying catalytic processes and catalysts, the chemistry of catalysts and adsorbent surfaces, the structure and physicochemical properties of catalysts, preparation and poisoning of catalysts, macrokinetics, and computer simulations in catalysis. The journal also publishes review articles on contemporary problems in kinetics and catalysis. The journal welcomes manuscripts from all countries in the English or Russian language.