Chapter V. Homogeneous and Heterogeneous Reactions between Active Particles in Gas Combustion

IF 1.3 4区化学 Q4 CHEMISTRY, PHYSICAL

Kinetics and Catalysis Pub Date : 2024-08-20 DOI:10.1134/S0023158424601293

V. V. Azatyan

引用次数: 0

Abstract

The formation of atoms and radicals in the flame in concentrations by many orders of magnitude higher than the equilibrium values at combustion temperatures is explained. Results that prove the important role of homogeneous and heterogeneous reactions between atoms and radicals in combustion are presented. The decisive role of previously unknown reactions of heterogeneous chain propagation in combustion is illustrated by experimental results. The reasons for the misconceptions of several foreign and Russian authors who tried to deny chain combustion are explained.

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第 V 章气体燃烧中活性粒子之间的均相和异相反应

摘要解释了火焰中原子和自由基的形成，其浓度比燃烧温度下的平衡值高出许多数量级。研究结果证明了原子和自由基之间的同相和异相反应在燃烧中的重要作用。实验结果说明了以前未知的异质链传播反应在燃烧中的决定性作用。解释了一些试图否认链式燃烧的外国和俄罗斯作者的错误观点的原因。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Kinetics and Catalysis 化学-物理化学

CiteScore

2.10

自引率

27.30%

发文量

审稿时长

6-12 weeks

期刊介绍： Kinetics and Catalysis Russian is a periodical that publishes theoretical and experimental works on homogeneous and heterogeneous kinetics and catalysis. Other topics include the mechanism and kinetics of noncatalytic processes in gaseous, liquid, and solid phases, quantum chemical calculations in kinetics and catalysis, methods of studying catalytic processes and catalysts, the chemistry of catalysts and adsorbent surfaces, the structure and physicochemical properties of catalysts, preparation and poisoning of catalysts, macrokinetics, and computer simulations in catalysis. The journal also publishes review articles on contemporary problems in kinetics and catalysis. The journal welcomes manuscripts from all countries in the English or Russian language.