Chapter V. Homogeneous and Heterogeneous Reactions between Active Particles in Gas Combustion

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2024-08-20 DOI:10.1134/S0023158424601293

V. V. Azatyan

引用次数: 0

Abstract

The formation of atoms and radicals in the flame in concentrations by many orders of magnitude higher than the equilibrium values at combustion temperatures is explained. Results that prove the important role of homogeneous and heterogeneous reactions between atoms and radicals in combustion are presented. The decisive role of previously unknown reactions of heterogeneous chain propagation in combustion is illustrated by experimental results. The reasons for the misconceptions of several foreign and Russian authors who tried to deny chain combustion are explained.

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第 V 章气体燃烧中活性粒子之间的均相和异相反应

摘要解释了火焰中原子和自由基的形成，其浓度比燃烧温度下的平衡值高出许多数量级。研究结果证明了原子和自由基之间的同相和异相反应在燃烧中的重要作用。实验结果说明了以前未知的异质链传播反应在燃烧中的决定性作用。解释了一些试图否认链式燃烧的外国和俄罗斯作者的错误观点的原因。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

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