{"title":"On the Possibility of Measuring the Electronic Work Function of Nonvolatile Materials by High-Temperature Mass Spectrometry","authors":"A. Ya. Borshchevskii","doi":"10.1134/S0036024424701061","DOIUrl":null,"url":null,"abstract":"<p>The possibility of measuring the work function of metals and salt systems by measuring the partial pressures of the ionic component of the gas phase using the Knudsen effusion method combined with mass spectrometric analysis of evaporation products was studied. The main sources of erroneous data are analyzed. Various determinations of the electronic work function and the relationship between them are considered.</p>","PeriodicalId":767,"journal":{"name":"Russian Journal of Physical Chemistry A","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry A","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036024424701061","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The possibility of measuring the work function of metals and salt systems by measuring the partial pressures of the ionic component of the gas phase using the Knudsen effusion method combined with mass spectrometric analysis of evaporation products was studied. The main sources of erroneous data are analyzed. Various determinations of the electronic work function and the relationship between them are considered.
期刊介绍:
Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world.
Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.