Performance regulation of the TFC NF membrane via the introduction of oleic acid into different organic solvents
IF 2.8
4区 生物学
Q3 BIOTECHNOLOGY & APPLIED MICROBIOLOGY
Yandong Lu, Jiaxu Ning, Yue Zong, Fu Ding, Gaige Liu, Ruijun Zhang
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Abstract
BACKGROUNDTailored design of high‐performance nanofiltration membranes is desirable. The physicochemical properties of the organic phaseare essential for the preparation of nanofiltration membranes. Therefore, byfine‐tuning the organic phase, it is possible to achieve nanofiltrationmembranes with enhanced performance.RESULTSIn this work, oleic acid, a naturally extracted fatty acid, wasintroduced into three different organic solvents (n‐heptane, n‐octane andisopar G) to construct special oil phases for interfacial polymerization. Testingresults showed that proper dosage of oleic acid addition can effectivelydecrease the nanofiltration membrane pore size and enhance the salt rejectionregardless of the solvent type. Taking n‐octane as example, 5% oleic acidaddition in it can decrease the mean pore size from 0.500 nm to 0.341 nm and improve the MgSO4 rejection from 52.4% to 95.5%. Further characterizationindicated that the introduction of oleic acid into organic solvent cansignificantly reduce the interfacial tension and promote the diffusion of piperazinefrom aqueous phase to the oil phase. In addition, oleic acid could react with piperazineand produce some white particles that could be embed into the polyamide layer, thus altering the surface morphology.CONCLUSIONIn this work, a novel modified thin film composite nanofiltration membrane was prepared by a simple and controllable oleic acid assisted interfacial polymerization strategy, which exhibits good water permeability, solute selectivity and antifouling property. Without changing the existing process, our strategy opens up a simple, environmentally friendly and operable route for the synthesis of thin film composite nanofiltration membranes. © 2024 Society of Chemical Industry (SCI).
通过在不同有机溶剂中引入油酸调节 TFC NF 膜的性能
背景高性能纳滤膜的定制设计非常理想。有机相的物理化学特性对纳滤膜的制备至关重要。结果在这项工作中,将天然提取的脂肪酸油酸引入三种不同的有机溶剂(正庚烷、正辛烷和异帕 G)中,构建了用于界面聚合的特殊油相。测试结果表明,无论使用哪种溶剂,适当添加油酸都能有效降低纳滤膜的孔径,提高纳滤膜的拒盐能力。以正辛烷为例,添加 5%的油酸可将平均孔径从 0.500 nm 减小到 0.341 nm,并将 MgSO4 的截留率从 52.4% 提高到 95.5%。进一步的表征表明,在有机溶剂中加入油酸可以显著降低界面张力,促进哌嗪从水相扩散到油相。此外,油酸还能与哌嗪发生反应,生成一些白色颗粒嵌入聚酰胺层中,从而改变表面形态。在不改变现有工艺的前提下,我们的策略为薄膜复合纳滤膜的合成开辟了一条简单、环保、可操作的途径。© 2024 化学工业学会(SCI)。
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