Daniel Lozano-Martín, Rodrigo Susial, Pedro Hernández, Teresa E. Fernández-Vicente, M. Carmen Martín, José J. Segovia
{"title":"Speed of sound and phase equilibria for ($CO_{2}$ + $C_{3}H_{8}$) mixtures","authors":"Daniel Lozano-Martín, Rodrigo Susial, Pedro Hernández, Teresa E. Fernández-Vicente, M. Carmen Martín, José J. Segovia","doi":"arxiv-2409.04083","DOIUrl":null,"url":null,"abstract":"This work presents phase envelope and speed of sound data for the (0.60\n$CO_{2}$ + 0.40 $C_{3}H_{8}$) and (0.80 $CO_{2}$ + 0.20 $C_{3}H_{8}$) binary\nmixtures. Phase equilibria was measured using a cylindrical resonator working\nin the microwave band whereas an acoustic resonator was used for speed of sound\nmeasurements. The experimental results were compared with GERG-2008 equation of\nstate, obtaining average absolute deviations by 0.24% in pressure for phase\nequilibria data and 0.025% for speed of sound data. Speed of sound values were\nused to derive perfect-gas heat capacities, acoustic virial coefficients, and\nsecond density virial coefficients. In addition, AGA8-DC92 equation of state\nperformance was checked for the results derived from speeds of sound.","PeriodicalId":501304,"journal":{"name":"arXiv - PHYS - Chemical Physics","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"arXiv - PHYS - Chemical Physics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/arxiv-2409.04083","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
This work presents phase envelope and speed of sound data for the (0.60
$CO_{2}$ + 0.40 $C_{3}H_{8}$) and (0.80 $CO_{2}$ + 0.20 $C_{3}H_{8}$) binary
mixtures. Phase equilibria was measured using a cylindrical resonator working
in the microwave band whereas an acoustic resonator was used for speed of sound
measurements. The experimental results were compared with GERG-2008 equation of
state, obtaining average absolute deviations by 0.24% in pressure for phase
equilibria data and 0.025% for speed of sound data. Speed of sound values were
used to derive perfect-gas heat capacities, acoustic virial coefficients, and
second density virial coefficients. In addition, AGA8-DC92 equation of state
performance was checked for the results derived from speeds of sound.