Thermal Stability of Ammonium Ionic Liquids with Ferrocenyl Methyl Radical in the Cation

L. I. Voronchikhina, A. S. Gryaznov, O. E. Zhuravlev
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Abstract

New ammonium ionic liquids with a ferrocenylmethyl radical in the cation with different long hydrophobic chains (C7H15, C12H25, and C16H33) were prepared. The thermal stability of the compounds in air in the temperature range 20–500°C was studied in comparison with an ionic liquid with the benzyl radical in the cation. A higher thermal stability of dimethylferrocenylmethylalkylammonium chlorides was shown in comparison with benzalkonium.

Abstract Image

阳离子中含有二茂铁甲基自由基的铵离子液体的热稳定性
摘要 制备了阳离子中含有二茂铁甲基自由基和不同长疏水链(C7H15、C12H25 和 C16H33)的新型铵离子液体。与阳离子中含有苄基自由基的离子液体相比,研究了这些化合物在空气中 20-500°C 温度范围内的热稳定性。结果表明,二甲基二茂铁甲基烷基氯化铵的热稳定性高于苯扎氯铵。
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