Multimodal anti-counterfeiting and optical storage application based on luminescence reversible modification and color change of photochromic phosphor

Abstract

Reversible upconversion luminescence (RUCL) modification based on photochromism has received considerable interest due to its potential applications in optical storage and invisible optical anti-counterfeiting. Herein, white β-BaScAlO: Yb, Er (β-BSAO-YE) phosphor was irradiated with 254 nm light, which caused the phosphor to turn blue due to the increase of oxygen vacancy. The blue β-BSAO-YE phosphor returns to its original color upon stimulation with 808 nm laser light or 125 °C, exhibiting a double photo-induced reversible photochromic change. The green and red upconversion luminescence (UCL) of the β-BSAO-YE were reversibly modified according to their photochromic properties. The UCL modification changes the luminescence color of the pattern, indicating that β-BSAO-YE phosphor is an ideal compound anti-counterfeit agent. The light information recorded on the β-BSAO-YE binary photochromic dot matrix can be read under ultraviolet (UV) and near-infrared (NIR) excitation, demonstrating the potential application of β-BSAO-YE phosphors as optical data storage media. In addition, the cyclic experiment showed good photochromic and UCL modulation repeatability. The new luminescent β-BSAO-YE not only proposes a new way to exploring upconversion red light materials, but also provides new materials for optical storage, optical information and optical anti-counterfeiting.