Piezoresistive PtSe$_2$ pressure sensors with reliable high sensitivity and their integration into CMOS ASIC substrates

Sebastian Lukas, Nico Rademacher, Sofía Cruces, Michael Gross, Eva Desgué, Stefan Heiserer, Nikolas Dominik, Maximilian Prechtl, Oliver Hartwig, Cormac Ó Coileáin, Tanja Stimpel Lindner, Pierre Legagneux, Arto Rantala, Juha Matti Saari, Miika Soikkeli, Georg S. Duesberg, Max C. Lemme
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Abstract

Membrane-based sensors are an important market for microelectromechanical systems (MEMS). Two-dimensional (2D) materials, with their low mass, are excellent candidates for suspended membranes to provide high sensitivity, small footprint sensors. The present work demonstrates pressure sensors employing large-scale-synthesized 2D platinum diselenide (PtSe${_2}$) films as piezoresistive membranes supported only by a thin polymer layer. We investigate three different synthesis methods with contrasting growth parameters and establish a reliable high yield fabrication process for suspended PtSe${_2}$/PMMA membranes across sealed cavities. The pressure sensors reproducibly display sensitivities above 6 x 10${^4}$ kPa. We show that the sensitivity clearly depends on the membrane diameter and the piezoresistive gauge factor of the PtSe${_2}$ film. Reducing the total device size by decreasing the number of membranes within a device leads to a significant increase in the area-normalized sensitivity. This allows the manufacturing of pressure sensors with high sensitivity but a much smaller device footprint than the current state-of-the-art MEMS technology. We further integrate PtSe${_2}$ pressure sensors with CMOS technology, improving the technological readiness of PtSe${_2}$-based MEMS and NEMS devices.
具有可靠高灵敏度的压阻 PtSe$_2$ 压力传感器及其与 CMOS ASIC 基底面的集成
基于膜的传感器是微机电系统(MEMS)的一个重要市场。二维(2D)材料质量小,是悬浮膜的最佳候选材料,可提供高灵敏度、小尺寸的传感器。本研究展示了采用大规模合成的二维二硒化铂(PtSe${_2}$)薄膜作为仅由薄聚合物层支撑的频阻膜的压力传感器。我们研究了具有不同生长参数的三种不同合成方法,并建立了一种可靠的高产率制造工艺,用于制造密封空腔中的悬浮式 PtSe${_2}$/PMMA 膜。压力传感器的灵敏度超过 6 x 10${^4}$ kPa。我们的研究表明,灵敏度明显取决于膜的直径和 PtSe${_2}$ 薄膜的压阻测量因子。通过减少器件内膜的数量来减小器件的总尺寸,可显著提高面积归一化灵敏度。这样就能制造出具有高灵敏度的压力传感器,但器件占地面积却比目前最先进的 MEMS 技术小得多。我们进一步将 PtSe${_2}$ 压力传感器与 CMOS 技术相结合,提高了基于 PtSe${_2}$ 的 MEMS 和 NEMS 器件的技术成熟度。
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