Mixture of biochar as a green additive in cement-based materials for carbon dioxide sequestration

Abstract

Cement production for concrete is one of the main reasons why the building industry contributes significantly to carbon dioxide emissions. This paper investigates an innovative approach to utilizing CO₂ by incorporating mixed biochar in mortar. Various dosages (0%, 3%, 5%, and 10%) of mixed biochar were explored to assess their impact on the structural properties and environmental sustainability. In this study, mixed biochar was prepared using the pyrolysis method, in which biomasses (rice husk and sawdust) were heated in the absence of oxygen for 2 h in a muffle furnace at the heating rate of 10 ℃/min to 550 ℃ with a 2-h holding time. The replacement of biochar was done with cement in a mortar mixture for casting the cubes followed by putting them in the carbonation chamber for 28 days curing. After that, the cured samples were tested for mechanical strength, porosity, density, and water absorption. X-ray diffraction (XRD) and thermo-gravimetric analysis (TGA) showed that biochar supplementation promoted cement hydration products. Field emission scanning electron microscope (FESEM) analysis showed that several cement hydrates such as C-S–H, Ca(OH)₂, and CaCO₃ were formed with different doses of biochar and increased mechanical strength. Addition of 10 wt. % biochar increased the compressive strength of the composite by 24.2% than the control respectively, and successfully promoted the CO₂ sequestration with 6% CO₂ uptake after 28 days of accelerated CO₂ curing. The present research has shown the benefits of optimally integrating mixed biochar with cement in the development of low-carbon, sustainable cementitious materials that have the potential to convert building materials like concrete in the future.