Nano-micro pore structure characteristics of carbon black and recycled carbon fiber reinforced alkali-activated materials

Weiwei Zhang, Binbin Yin, Arslan Akbar, Wen-Wei Li, Yitao Dai, K. M. Liew
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Abstract

Microscopic scrutiny aids in alkali-activated materials’ (AAM) application in construction industry. This study delves into the pore structure and properties of one-part alkali-activated slag (AAS) mortar modified by carbon black (CB) and recycled carbon fiber (rCF). The additives enhanced flexural strength by 51.82% (12.16 MPa) with lower water absorption (10.24%). Refinement of pore size and reduction of connectivity are key factors in improving properties. The densification effect of CB and the strong interface between rCF and gel were observed. Furthermore, AAS mortars exhibited multifractal characteristics within the range of micropores and capillary pores. Despite altering fractal regions, the additives did not affect its size dependence. The backbone fractal dimension increases with the addition of CB and rCF, exhibiting strong correlations with various macro properties, thus serving as a comprehensive parameter to characterize pore shape and distribution. This study deepens understanding of AAM composites, facilitating their adoption of low-carbon building materials.

Abstract Image

炭黑和再生碳纤维增强碱活性材料的纳米微孔结构特征
显微镜观察有助于碱活性材料(AAM)在建筑业中的应用。本研究探讨了由炭黑(CB)和再生碳纤维(rCF)改性的单组分碱活性矿渣(AAS)砂浆的孔隙结构和性能。添加剂提高了 51.82% 的抗折强度(12.16 兆帕),同时降低了吸水率(10.24%)。细化孔径和降低连通性是改善性能的关键因素。在此过程中观察到了 CB 的致密化效应以及 rCF 与凝胶之间的牢固界面。此外,AAS 砂浆在微孔和毛细孔范围内表现出多分形特征。尽管改变了分形区域,但添加剂并不影响其尺寸依赖性。骨架分形维度随着 CB 和 rCF 的添加而增大,与各种宏观特性表现出很强的相关性,因此可作为表征孔隙形状和分布的综合参数。这项研究加深了人们对 AAM 复合材料的理解,有助于其在低碳建筑材料中的应用。
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