Synthesis and comparison of copper precursor using aminoalkoxide for copper containing thin films and nanomaterials

IF 2.1 3区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Organometallic Chemistry Pub Date : 2024-08-26 DOI:10.1016/j.jorganchem.2024.123347

Haesun Kim , Yurim Mo , Sunyoung Shin , Seung Uk Son , Ji Yeon Ryu , Taek-Mo Chung , Seon Joo Lee , Bo Keun Park

引用次数: 0

Abstract

Cu(dmamp')₂ (1) (dmamp' = 2-(dimethylamino)-2-methyl-1-propoxide) was synthesized for comparison according to the position of the substituent of aminoalkoxide. When comparing the properties such as structure, thermal stability, and usability with 1 and the previously reported Cu(dmamp)₂ (dmamp = 1-dimethylamino-2-methyl-2-propoxide), other properties were similar, but 1 had better thermal stability. Consequently, 1 is thought to be a better precursor for thin films and nanomaterials containing Cu.

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使用氨基氧化烷合成含铜薄膜和纳米材料的铜前驱体并进行比较

根据氨基氧化物取代基的位置合成了 Cu(dmamp')2 (1)（dmamp' = 2-（二甲基氨基）-2-甲基-1-丙氧基）进行比较。在比较 1 和之前报道的 Cu(dmamp)2（dmamp = 1-二甲基氨基-2-甲基-2-丙氧基）的结构、热稳定性和可用性等特性时，发现其他特性相似，但 1 的热稳定性更好。因此，1 被认为是含铜薄膜和纳米材料的更好前体。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Organometallic Chemistry 化学-无机化学与核化学

CiteScore

4.40

自引率

8.70%

发文量

221

审稿时长

36 days

期刊介绍： The Journal of Organometallic Chemistry targets original papers dealing with theoretical aspects, structural chemistry, synthesis, physical and chemical properties (including reaction mechanisms), and practical applications of organometallic compounds. Organometallic compounds are defined as compounds that contain metal - carbon bonds. The term metal includes all alkali and alkaline earth metals, all transition metals and the lanthanides and actinides in the Periodic Table. Metalloids including the elements in Group 13 and the heavier members of the Groups 14 - 16 are also included. The term chemistry includes syntheses, characterizations and reaction chemistry of all such compounds. Research reports based on use of organometallic complexes in bioorganometallic chemistry, medicine, material sciences, homogeneous catalysis and energy conversion are also welcome. The scope of the journal has been enlarged to encompass important research on organometallic complexes in bioorganometallic chemistry and material sciences, and of heavier main group elements in organometallic chemistry. The journal also publishes review articles, short communications and notes.