Preparation and sodium storage properties of Ni-CoFe2O4/Reduced graphene oxide

Abstract

The Ni-doped CoFe₂O₄ graphene composites (Ni-CFO/RGO) have been successfully prepared using the microwave-assisted method. The substance is a novel nanocomposite structure in which CoFe₂O₄ nanoparticles are tightly and uniformly attached to graphene hybrid nanosheets. The synergistic effect of Ni doping and CoFe₂O₄ can reduce the volume expansion of CoFe₂O₄ in the reaction process and inhibit the stacking of graphene. Because the Ni-CFO/RGO composite is structurally stable during the electrochemical reaction, it has a good theoretical capacity. Excellent carbon composite can further enhance the electron transport performance and structural stability of the material, thereby improving the electrochemical performance and cycle life of the material. Doping Ni²⁺ into metal oxides can not only form oxygen vacancies, and improve the transport capacity of sodium ions, but also broaden the electron transport channel. In addition, the catalyst can form a composite structure with metal oxide, which can effectively inhibit its volume expansion. At the same time, reacting with carbon materials, can also effectively reduce the accumulation of carbon, thereby reducing its resistance. After 200 cycles at a current density of 0.05 A g⁻¹, it can provide a high sodium storage capacity of 380.6 mAh g⁻¹, which still keeps 203.4 mAh g⁻¹ at 1.5 A g⁻¹.