Influence of substitution of Cr by Cu on phase equilibria and microstructures in the Fe–Ni–Co–Cr high-entropy alloys

IF 4.3 2区 材料科学 Q2 CHEMISTRY, PHYSICAL
Antonín Záděra , Jiří Sopoušek , Jiří Buršík , Jan Čupera , Pavel Brož , Vít Jan
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引用次数: 0

Abstract

The article describes how substitution of chromium by copper affects phase equilibria in Fe–Ni–Co–Cr high-entropy alloy. The alloys with copper content ranging from 0 to 20 % (at.) of Cu were prepared. The alloys were equilibrated at 900, 800, 700, and 650 °C. The samples were investigated by electron microscopy, EDX spectroscopy, and EBSD method. The face-centred cubic phases have only occurred in equilibrated alloys: austenite matrix, copper-rich FCC(Cu) phase, and regions containing these phases. The compositions of equilibrated samples at annealing temperatures are given. Fine microstructures including a semicoherent FCC phase rich in Cu and an FCC phase including the main magnetic elements (Fe, Co, Ni) were formed. The experimental results were compared with the calculated phase equilibria obtained by the CALPHAD method.

Abstract Image

用铜替代铬对铁-镍-钴-铬高熵合金相平衡和显微结构的影响
文章介绍了铜代铬如何影响铁-镍-钴-铬高熵合金中的相平衡。研究人员制备了铜含量为 0% 至 20% (at.) 的合金。合金分别在 900、800、700 和 650 °C 下进行平衡。采用电子显微镜、EDX 光谱和 EBSD 方法对样品进行了研究。平衡合金中只出现了面心立方相:奥氏体基体、富铜 FCC(Cu) 相以及含有这些相的区域。给出了退火温度下平衡样品的成分。形成了精细的微观结构,包括富含铜的半固态 FCC 相和包含主要磁性元素(铁、钴、镍)的 FCC 相。实验结果与通过 CALPHAD 方法计算得出的相平衡进行了比较。
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来源期刊
Intermetallics
Intermetallics 工程技术-材料科学:综合
CiteScore
7.80
自引率
9.10%
发文量
291
审稿时长
37 days
期刊介绍: This journal is a platform for publishing innovative research and overviews for advancing our understanding of the structure, property, and functionality of complex metallic alloys, including intermetallics, metallic glasses, and high entropy alloys. The journal reports the science and engineering of metallic materials in the following aspects: Theories and experiments which address the relationship between property and structure in all length scales. Physical modeling and numerical simulations which provide a comprehensive understanding of experimental observations. Stimulated methodologies to characterize the structure and chemistry of materials that correlate the properties. Technological applications resulting from the understanding of property-structure relationship in materials. Novel and cutting-edge results warranting rapid communication. The journal also publishes special issues on selected topics and overviews by invitation only.
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