Bio-synthesized ZnO in cesium based perovskite solar cells: A pathway to sustainable high efficiency

IF 2.1 4区 物理与天体物理 Q3 PHYSICS, CONDENSED MATTER
Sagar Bhattarai , Mustafa K.A. Mohammed , Ismail Hossain , Pratap Kumar Dakua , Rahul Pandey , Jaya Madan
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Abstract

Photovoltaics (PV) having perovskite material have an enormous influence on the progress in solar cell technology. Excluding the high efficiency, stability, and flexibility, the extended impact has now been given on utilizing lead-free environmentally suitable, and much cheaper materials for the PSC fabrication. The material with a volatile free, that is, cesium tin iodide (CsSnI3), is capable for the fabrication of the Perovskite Solar Cell that creates eco-friendly as well as enhanced optical-electronic features for the low bandgap, that is 1.27eV. Sn could increase the steadiness of the lead-free perovskite. However, as widely known, Sn2+ always suffers from oxidation with I2 and O2 and induces instability issues. In the ongoing work, cesium tin iodide, is employed as the primary absorber, in so much the root-extracted naturally manufactured ZnO is used as ETM for less cost in production. Correspondingly, Spiro-OMeTAD is used as HTM for enhancement in hole collection in the device. The inclusive numerical simulation with the bio-synthesized ZnO-NP can be applied in designing the solar cell having an applicable thickness of CsSnI3, suitable temperature, total defect density, and the influence of the resistance, respectively. The current simulation of PSC offers the extraordinary power conversion efficiency (η) of 26.40 % considering CsSnI3 as the absorber. The results described in this investigation may confirm an effective approach to design and the expansion of the lead-free PSC.

铯基包晶石太阳能电池中的生物合成氧化锌:实现可持续高效率的途径
采用过氧化物晶体材料的光伏(PV)技术对太阳能电池技术的进步有着巨大的影响。除了高效率、稳定性和灵活性之外,利用无铅、环保、成本更低的材料制造 PSC 也产生了巨大的影响。碘化铯锡(CsSnI3)是一种不含挥发性物质的材料,可用于制造透辉石太阳能电池,它既环保,又能增强低带隙即 1.27eV 的光电特性。锡可以提高无铅过氧化物的稳定性。然而,众所周知,Sn2+ 总是会被 I2 和 O2 氧化,从而引发不稳定问题。在正在进行的工作中,采用了碘化铯锡作为主要吸收剂,同时使用从根部提取的天然制造的氧化锌作为 ETM,以降低生产成本。相应地,为了提高设备的孔收集能力,使用了螺-OMeTAD 作为 HTM。利用生物合成的 ZnO-NP 进行的综合数值模拟可用于设计太阳能电池,并分别考虑 CsSnI3 的适用厚度、合适的温度、总缺陷密度和电阻的影响。以 CsSnI3 为吸收体,目前模拟的 PSC 功率转换效率 (η) 为 26.40%。本研究中描述的结果可能证实了一种设计和扩展无铅 PSC 的有效方法。
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来源期刊
Solid State Communications
Solid State Communications 物理-物理:凝聚态物理
CiteScore
3.40
自引率
4.80%
发文量
287
审稿时长
51 days
期刊介绍: Solid State Communications is an international medium for the publication of short communications and original research articles on significant developments in condensed matter science, giving scientists immediate access to important, recently completed work. The journal publishes original experimental and theoretical research on the physical and chemical properties of solids and other condensed systems and also on their preparation. The submission of manuscripts reporting research on the basic physics of materials science and devices, as well as of state-of-the-art microstructures and nanostructures, is encouraged. A coherent quantitative treatment emphasizing new physics is expected rather than a simple accumulation of experimental data. Consistent with these aims, the short communications should be kept concise and short, usually not longer than six printed pages. The number of figures and tables should also be kept to a minimum. Solid State Communications now also welcomes original research articles without length restrictions. The Fast-Track section of Solid State Communications is the venue for very rapid publication of short communications on significant developments in condensed matter science. The goal is to offer the broad condensed matter community quick and immediate access to publish recently completed papers in research areas that are rapidly evolving and in which there are developments with great potential impact.
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