Study on Aquifer Contamination by Heavy Metals Using Finite Element Modeling with Freundlich Parameters in Traditional Metal Recycling Craft Village in Bac Ninh Province, Vietnam
Nguyen Bach Thao, Renat Shakirov, Nadezhda Syrbu, Tran Vu Long, Trinh Hoai Thu, Dao Duc Bang, Tran Quang Tuan, Duong Thi Thanh Thuy, Kieu Thi Van Anh, Vu Thu Hien, Natalia Lee
{"title":"Study on Aquifer Contamination by Heavy Metals Using Finite Element Modeling with Freundlich Parameters in Traditional Metal Recycling Craft Village in Bac Ninh Province, Vietnam","authors":"Nguyen Bach Thao, Renat Shakirov, Nadezhda Syrbu, Tran Vu Long, Trinh Hoai Thu, Dao Duc Bang, Tran Quang Tuan, Duong Thi Thanh Thuy, Kieu Thi Van Anh, Vu Thu Hien, Natalia Lee","doi":"10.1134/s1819714024700155","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>The traditional craft villages in Vietnam in general and in Bac Ninh province in particular have been exposing many negative impacts on the environment. The heavy metal-rich wastes from the metal recycling casting craft villages in the field of metal recycling and metal casting are causing severe heavy metal pollution not only to the air, soils, and sediments but also to the groundwater resources. In Da Hoi iron recycling craft village in Chau Khe ward, Tu Son town, Bac Ninh province, Vietnam, the Holocene aquifer is exposed to the Ngu Huyen Khe River’s sediments contaminated with heavy metals Lead, Cadmium, Nickel, and Zinc. Freundlich isotherm parameters of the Holocene aquifer have been selected for finite element modeling of heavy metal transport with high temporal and spatial varying retardation factors to get reliable quantitative heavy metals’ distribution in depth and time. Initial and boundary conditions have been augmented to be established. The retardation factors of the advection and dispersion transport in the Holocene aquifer for heavy metals Pb, Zn, Cd, and Ni are very highly none-linear and very much varying in time and space: 8.7–66.4 for Pb, 2.0–12 for Zn, 1.7–4.8 for Cd and 1.1–5.9 for Ni. The results of the numerical modeling show that heavy metal transport in the Holocene aquifer is very fast and the entire aquifer thickness has equilibrium aquifer formation and aquifer water heavy concentrations after around 2–2.5 years for Cd and Ni, around 4 years for Zn and around 27 years for Pb. The heavy metals’ fluxes from the Holocene aquifer to the Pleistocene aquifer are maximal and more or less constant from the equilibrium time and would cause severe contamination of the Pleistocene aquifer.</p>","PeriodicalId":49583,"journal":{"name":"Russian Journal of Pacific Geology","volume":"72 1","pages":""},"PeriodicalIF":0.9000,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Pacific Geology","FirstCategoryId":"89","ListUrlMain":"https://doi.org/10.1134/s1819714024700155","RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"GEOSCIENCES, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The traditional craft villages in Vietnam in general and in Bac Ninh province in particular have been exposing many negative impacts on the environment. The heavy metal-rich wastes from the metal recycling casting craft villages in the field of metal recycling and metal casting are causing severe heavy metal pollution not only to the air, soils, and sediments but also to the groundwater resources. In Da Hoi iron recycling craft village in Chau Khe ward, Tu Son town, Bac Ninh province, Vietnam, the Holocene aquifer is exposed to the Ngu Huyen Khe River’s sediments contaminated with heavy metals Lead, Cadmium, Nickel, and Zinc. Freundlich isotherm parameters of the Holocene aquifer have been selected for finite element modeling of heavy metal transport with high temporal and spatial varying retardation factors to get reliable quantitative heavy metals’ distribution in depth and time. Initial and boundary conditions have been augmented to be established. The retardation factors of the advection and dispersion transport in the Holocene aquifer for heavy metals Pb, Zn, Cd, and Ni are very highly none-linear and very much varying in time and space: 8.7–66.4 for Pb, 2.0–12 for Zn, 1.7–4.8 for Cd and 1.1–5.9 for Ni. The results of the numerical modeling show that heavy metal transport in the Holocene aquifer is very fast and the entire aquifer thickness has equilibrium aquifer formation and aquifer water heavy concentrations after around 2–2.5 years for Cd and Ni, around 4 years for Zn and around 27 years for Pb. The heavy metals’ fluxes from the Holocene aquifer to the Pleistocene aquifer are maximal and more or less constant from the equilibrium time and would cause severe contamination of the Pleistocene aquifer.
期刊介绍:
Russian Journal of Pacific Geology publishes the results of research on the Earth crust and mantle composition and provides articles on the geological structure and patterns of distribution of mineral deposits in the Pacific Ocean, marginal seas and continental margins. It discusses the topics of stratigraphy, sedimentology, magmatic activity, and seismicity. The journal deals with the problems of lithosphere plates tectonics, and offers the results of neotectonic, geomorphological, geodesic, environmental and mining studies in the Pacific region. The journal accepts theoretical, methodical and philosophical articles covering general issues of geology, geophysics, geochemistry, geoecology and mining. The journal also publishes critical notes and comments, and reviews.