Influence of Y2O3 and Cr2O3 on Formation of Microstructure and Properties as well as Accuracy of Reproduction of Geometric Characteristics during 3D Printing with Ceramics Based on Al2O3–ZrO2

IF 0.5 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY
N. L. Kotelnikov, M. A. Goldberg, T. O. Obolkina, S. V. Smirnov, O. S. Antonova, S. M. Barinov, V. S. Komlev
{"title":"Influence of Y2O3 and Cr2O3 on Formation of Microstructure and Properties as well as Accuracy of Reproduction of Geometric Characteristics during 3D Printing with Ceramics Based on Al2O3–ZrO2","authors":"N. L. Kotelnikov,&nbsp;M. A. Goldberg,&nbsp;T. O. Obolkina,&nbsp;S. V. Smirnov,&nbsp;O. S. Antonova,&nbsp;S. M. Barinov,&nbsp;V. S. Komlev","doi":"10.1134/S2075113324700564","DOIUrl":null,"url":null,"abstract":"<p><b>Abstract</b>—Powders and ceramic composite materials in an Al<sub>2</sub>O<sub>3</sub>–ZrO<sub>2</sub> system with a concentration of ZrO<sub>2</sub> of 20 wt % are obtained. The effect of introduction of chromium oxide and yttrium oxide into Al<sub>2</sub>O<sub>3</sub>–ZrO<sub>2</sub> ceramic materials on the phase composition, porosity, microstructure, and mechanical properties is studied. It is shown that the introduction of chromium oxide leads to the improvement of sintering and mechanical properties of the ceramic. Products with the predefined shape of a corresponding computer model are obtained by 3D printing, and also their multistage thermal treatment is carried out. Densely sintered ceramic materials are obtained at 1550 and 1600°C, the open porosity of which is below 1% and microhardness is up to 1646 ± 50 HV. The samples are characterized by a dense microstructure with the grain size of zirconium dioxide from 400 nm to 2 μm and of aluminum oxide from 800 nm to 3 μm. The thickness of the layer formed during 3D printing shows a positive impact of the addition of Cr<sub>2</sub>O<sub>3</sub> on the resolution during 3D printing.</p>","PeriodicalId":586,"journal":{"name":"Inorganic Materials: Applied Research","volume":"15 4","pages":"1031 - 1038"},"PeriodicalIF":0.5000,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Materials: Applied Research","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1134/S2075113324700564","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract—Powders and ceramic composite materials in an Al2O3–ZrO2 system with a concentration of ZrO2 of 20 wt % are obtained. The effect of introduction of chromium oxide and yttrium oxide into Al2O3–ZrO2 ceramic materials on the phase composition, porosity, microstructure, and mechanical properties is studied. It is shown that the introduction of chromium oxide leads to the improvement of sintering and mechanical properties of the ceramic. Products with the predefined shape of a corresponding computer model are obtained by 3D printing, and also their multistage thermal treatment is carried out. Densely sintered ceramic materials are obtained at 1550 and 1600°C, the open porosity of which is below 1% and microhardness is up to 1646 ± 50 HV. The samples are characterized by a dense microstructure with the grain size of zirconium dioxide from 400 nm to 2 μm and of aluminum oxide from 800 nm to 3 μm. The thickness of the layer formed during 3D printing shows a positive impact of the addition of Cr2O3 on the resolution during 3D printing.

Abstract Image

Abstract Image

使用基于 Al2O3-ZrO2 的陶瓷进行 3D 打印时,Y2O3 和 Cr2O3 对微观结构和性能的形成以及几何特征再现精度的影响
摘要-在 ZrO2 浓度为 20 wt % 的 Al2O3-ZrO2 体系中获得了粉末和陶瓷复合材料。研究了在 Al2O3-ZrO2 陶瓷材料中引入氧化铬和氧化钇对相组成、孔隙率、微观结构和机械性能的影响。结果表明,引入氧化铬可改善陶瓷的烧结和机械性能。通过三维打印获得了具有相应计算机模型预定形状的产品,并对其进行了多级热处理。在 1550 和 1600°C 温度下获得了致密烧结陶瓷材料,其开放孔隙率低于 1%,显微硬度高达 1646 ± 50 HV。样品具有致密的微观结构,二氧化锆的晶粒尺寸从 400 纳米到 2 微米不等,氧化铝的晶粒尺寸从 800 纳米到 3 微米不等。三维打印过程中形成的层厚度表明,添加 Cr2O3 对三维打印过程中的分辨率有积极影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Inorganic Materials: Applied Research
Inorganic Materials: Applied Research Engineering-Engineering (all)
CiteScore
0.90
自引率
0.00%
发文量
199
期刊介绍: Inorganic Materials: Applied Research  contains translations of research articles devoted to applied aspects of inorganic materials. Best articles are selected from four Russian periodicals: Materialovedenie, Perspektivnye Materialy, Fizika i Khimiya Obrabotki Materialov, and Voprosy Materialovedeniya  and translated into English. The journal reports recent achievements in materials science: physical and chemical bases of materials science; effects of synergism in composite materials; computer simulations; creation of new materials (including carbon-based materials and ceramics, semiconductors, superconductors, composite materials, polymers, materials for nuclear engineering, materials for aircraft and space engineering, materials for quantum electronics, materials for electronics and optoelectronics, materials for nuclear and thermonuclear power engineering, radiation-hardened materials, materials for use in medicine, etc.); analytical techniques; structure–property relationships; nanostructures and nanotechnologies; advanced technologies; use of hydrogen in structural materials; and economic and environmental issues. The journal also considers engineering issues of materials processing with plasma, high-gradient crystallization, laser technology, and ultrasonic technology. Currently the journal does not accept direct submissions, but submissions to one of the source journals is possible.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信