Influence of Diffusion Alloying of Steel 20 in Medium of Low-Melting Liquid Metal Solutions by Elements of Ni–Cu System on Elemental Composition and Properties of Surface Layers

IF 0.5 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY
E. E. Bobylyov, I. D. Storojenko
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引用次数: 0

Abstract—The influence of diffusion saturation of steel 20 in the medium of low-melting liquid metal melts of Pb–Bi–Li–Ni–Cu composition on its elemental composition and corrosion resistance is considered in this article. As a result of diffusion saturation, a coating is formed structurally consisting of two zones: surface and transition ones. The surface zone contains 53% Cu, 30% Ni, and 17% Fe. As one approaches the transition zone, a decrease in the concentration of Cu and an increase in the concentration of Ni and Fe are observed. In this case, the transition zone structurally consists of inclusions of Fe in a Ni-based solid solution that did not pass into solid solution. In addition, there is a layer under the coating containing C in a higher concentration than the base material owing to the low solubility of C in solid solutions of the Cu–Ni–Fe system. The coating thickness ranges from 8 to 45 μm depending on the temperature and duration of saturation. It is also found that the resulting coatings can reduce the corrosion rate of samples from 3 to 0.8 mm/year.

Abstract Image

Abstract Image

镍铜系元素在低熔液态金属溶液介质中扩散合金化 20 号钢对表层元素组成和性能的影响
摘要--本文研究了 20 号钢在铅-铋-锂-镍-铜组成的低熔点液态金属熔体介质中的扩散饱和对其元素组成和耐腐蚀性的影响。扩散饱和的结果是形成了由表面区和过渡区两部分组成的涂层结构。表面区含有 53% 的铜、30% 的镍和 17% 的铁。当接近过渡区时,会发现铜的浓度下降,而镍和铁的浓度上升。在这种情况下,过渡区在结构上是由未进入固溶体的镍基固溶体中的铁夹杂物组成。此外,由于 C 在铜-镍-铁体系固溶体中的溶解度较低,涂层下还有一层 C,其浓度高于基体材料。涂层厚度从 8 微米到 45 微米不等,取决于温度和饱和持续时间。研究还发现,所产生的涂层可将样品的腐蚀速率从每年 3 毫米降低到每年 0.8 毫米。
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来源期刊
Inorganic Materials: Applied Research
Inorganic Materials: Applied Research Engineering-Engineering (all)
CiteScore
0.90
自引率
0.00%
发文量
199
期刊介绍: Inorganic Materials: Applied Research  contains translations of research articles devoted to applied aspects of inorganic materials. Best articles are selected from four Russian periodicals: Materialovedenie, Perspektivnye Materialy, Fizika i Khimiya Obrabotki Materialov, and Voprosy Materialovedeniya  and translated into English. The journal reports recent achievements in materials science: physical and chemical bases of materials science; effects of synergism in composite materials; computer simulations; creation of new materials (including carbon-based materials and ceramics, semiconductors, superconductors, composite materials, polymers, materials for nuclear engineering, materials for aircraft and space engineering, materials for quantum electronics, materials for electronics and optoelectronics, materials for nuclear and thermonuclear power engineering, radiation-hardened materials, materials for use in medicine, etc.); analytical techniques; structure–property relationships; nanostructures and nanotechnologies; advanced technologies; use of hydrogen in structural materials; and economic and environmental issues. The journal also considers engineering issues of materials processing with plasma, high-gradient crystallization, laser technology, and ultrasonic technology. Currently the journal does not accept direct submissions, but submissions to one of the source journals is possible.
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