Development of Cast AZ63 Magnesium Alloys for Cathodic Protection Applications via Alloying Additives

IF 1.6 4区 材料科学 Q2 Materials Science
Mohamed E. Moussa, Shimaa El-Hadad, Madiha A. Shoeib, Soha A. Abdel-Gawad
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Abstract

Applying sacrificial anodes to safeguard structures requires better exposure resistance. The effect of adding Ca (x = 0.1, 0.4, 0.7, and 1.0 wt%) and Ti (x = 0.1, 0.2, 0.3, 0.4, and 0.5 wt%) on the microstructure and electrochemical properties of AZ63 magnesium anode alloy has been studied. The corrosion resistance was examined in 3.5 wt% NaCl utilizing electrochemical impedance spectroscopy and potentiodynamic polarization. The microstructure of the base alloy, comprised of primary α-Mg and secondary phase Mg17Al12, extended to grain boundaries. The corrosion resistance was amended by adding the Ti element, which is correlated to the morphology and dispersion of the TiAl3 phase at the grain boundary. Adding Ca over 0.1 wt% increased the corrosion rate due to the formation of a highly reactive Mg2Ca phase. It implies that AZ63 alloy anodes are viable.

Abstract Image

通过合金添加剂开发用于阴极保护的铸造 AZ63 镁合金
应用牺牲阳极保护结构需要更好的抗曝露性。研究了添加 Ca(x = 0.1、0.4、0.7 和 1.0 wt%)和 Ti(x = 0.1、0.2、0.3、0.4 和 0.5 wt%)对 AZ63 镁阳极合金微观结构和电化学特性的影响。在 3.5 wt% 的 NaCl 溶液中,利用电化学阻抗光谱法和电位极化法对耐腐蚀性能进行了检测。基合金的微观结构由主相 α-Mg 和次相 Mg17Al12 组成,并延伸至晶界。加入 Ti 元素后,耐腐蚀性得到改善,这与晶界处 TiAl3 相的形态和分散有关。由于形成了高活性的 Mg2Ca 相,添加超过 0.1 wt% 的 Ca 会增加腐蚀速率。这意味着 AZ63 合金阳极是可行的。
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来源期刊
Transactions of The Indian Institute of Metals
Transactions of The Indian Institute of Metals Materials Science-Metals and Alloys
CiteScore
2.60
自引率
6.20%
发文量
3
期刊介绍: Transactions of the Indian Institute of Metals publishes original research articles and reviews on ferrous and non-ferrous process metallurgy, structural and functional materials development, physical, chemical and mechanical metallurgy, welding science and technology, metal forming, particulate technologies, surface engineering, characterization of materials, thermodynamics and kinetics, materials modelling and other allied branches of Metallurgy and Materials Engineering. Transactions of the Indian Institute of Metals also serves as a forum for rapid publication of recent advances in all the branches of Metallurgy and Materials Engineering. The technical content of the journal is scrutinized by the Editorial Board composed of experts from various disciplines of Metallurgy and Materials Engineering. Editorial Advisory Board provides valuable advice on technical matters related to the publication of Transactions.
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