Investigation of physical properties of microalgae-pectin-based bio-composite with addition of pine needle for environmental application

IF 4.6 Q2 MATERIALS SCIENCE, BIOMATERIALS
Carlos Munoz-Cupa, Kristine Lee, Anuradha Krishnan, Amarjeet Bassi
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Abstract

Polymers and biopolymers have gained significance due to their applicability and use in industry reducing the negative impact of polymers based on petroleum. A possible solution for the conventional polymer's biodegradability is bio-composites, which contain natural fibers or aggregates such as microalgae. Hence, microalgae biomass has a promising application to address the biodegradability issue of conventional polymers. In this study, Chlorella vulgaris biomass was mixed with pectin for control samples with glycerol as plasticizer. The mixture microalgae-pectin-glycerol, and the addition of pine needles was used to evaluate the tensile strength and compression of the bio-composite. This bio-composite showed a higher Young's modulus of 95.66 MPa for blend C2 and a higher strength with 20% of pectin concentration in the mixture. Additionally, the pine needle addition did not have a low effect between the compression results. On the other hand, analysis on elasticity showed that the full recovery of the bio-composite happened after 10 min in all the blends. Also, the bio-composite showed a slow release of nitrogen and phosphorous after 5 days of water addition, indicating an effective slow release for blend B for both nutrients. Water uptake capacity and loss of soluble material was studied using pullulan, chitosan, and cetyltrimethylammonium bromide additives. These cationic surfactants demonstrated their potential for reduction of water solubility of the bio-composite.

Abstract Image

添加松针的微藻-pectin 生物复合材料在环境应用中的物理性质研究
聚合物和生物聚合物由于其适用性和在工业中的应用,减少了以石油为基础的聚合物所带来的负面影响,因而变得越来越重要。生物复合材料是解决传统聚合物生物降解性问题的一个可行方案,它含有天然纤维或微藻等聚合体。因此,微藻生物质在解决传统聚合物的生物降解性问题方面具有广阔的应用前景。在这项研究中,对照样品中的小球藻生物质与果胶混合,甘油作为增塑剂。微藻-果胶-甘油混合物和松针被用来评估生物复合材料的拉伸强度和压缩性。这种生物复合材料显示,混合物 C2 的杨氏模量较高,为 95.66 兆帕,混合物中果胶浓度为 20% 时,强度较高。此外,松针添加量对压缩结果的影响并不明显。另一方面,弹性分析表明,在所有混合物中,生物复合材料在 10 分钟后完全恢复。此外,在加水 5 天后,生物复合材料显示出氮和磷的缓慢释放,这表明混合物 B 能有效地缓慢释放这两种养分。使用拉毛聚糖、壳聚糖和十六烷基三甲基溴化铵添加剂对吸水能力和可溶性物质的损失进行了研究。这些阳离子表面活性剂证明了它们在降低生物复合材料水溶性方面的潜力。
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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
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