Pyrazine-bridged polymetallic copper–iridium clusters

Abstract

The title mol­ecule is centrosymmetric, with a pyrazine ligand bridging two {Cu₁₀Ir₃} cluster units that are arranged in an unusual shape containing 13 vertices, 22 faces, and 32 sides.

Single crystals of the mol­ecular compound, {Cu₂₀Ir₆Cl₈(C₂₁H₂₄N₂)₆(C₄H₄N₂)₃]·3.18CH₃OH or [({Cu₁₀Ir₃}Cl₄(IMes)₃(pyrazine))₂(pyrazine)]·3.18CH₃OH [where IMes is 1,3-bis­(2,4,6-trimethylphen­yl)imidazol-2-yl­idene], with a unique heterometallic cluster have been prepared and the structure revealed using single-crystal X-ray diffraction. The mol­ecule is centrosymmetric with two {Cu₁₀Ir₃} cores bridged by a pyrazine ligand. The polymetallic cluster contains three stabilizing N-heterocyclic carbenes, four Cl ligands, and a non-bridging pyrazine ligand. Notably, the Cu—Ir core is arranged in an unusual shape containing 13 vertices, 22 faces, and 32 sides. The atoms within the trideca­metallic cluster are arranged in four planes, with 2, 4, 4, 3 metals in each plane. Ir atoms are present in alternate planes with an Ir atom featuring in the peripheral bimetallic plane, and two Ir atoms featuring on opposite sides of the non-adjacent tetra­metallic plane. The crystal contains two disordered methanol solvent mol­ecules with an additional region of non-modelled electron density corrected for using the SQUEEZE routine in PLATON [Spek (2015#). Acta Cryst. C71, 9–18]. The given chemical formula and other crystal data do not take into account the unmodelled methanol solvent mol­ecule(s).