N. M. Poghosyan, M. Dj. Poghosyan, A. H. Davtyan, S. D. Arsentev, L. N. Strekova, V. S. Arutyunov
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引用次数: 0
Abstract
The effect of the ratio of the reagents on a stabilized cool flame (CF) of rich propane-oxygen mixtures is investigated. It is found that with an increase in the initial concentration of propane in the mixture, its consumption, as well as the concentration of propylene, has a maximum at a ratio of C3H8 : O2 = 1 : 1. In this case, the selectivity of propylene formation reaches a maximum at a ratio of C3H8 : O2 = 4 : 1. It is shown that an increase in the initial propane concentration in the mixture increases the yield of methane, but reduces the yield of propylene, ethylene, hydrogen, CO, CO2, methanol, formaldehyde and acetaldehyde. At a ratio of C3H8 : O2 = 6 : 1, ethane was also found in the reaction products. The possibility of ethanol formation in the reactions of ethoxyl and hydroxyethyl radicals with acetaldehyde is analyzed using the CBS-QB3 quantum-chemical method.
期刊介绍：
Russian Journal of Physical Chemistry B: Focus on Physics is a journal that publishes studies in the following areas: elementary physical and chemical processes; structure of chemical compounds, reactivity, effect of external field and environment on chemical transformations; molecular dynamics and molecular organization; dynamics and kinetics of photoand radiation-induced processes; mechanism of chemical reactions in gas and condensed phases and at interfaces; chain and thermal processes of ignition, combustion and detonation in gases, two-phase and condensed systems; shock waves; new physical methods of examining chemical reactions; and biological processes in chemical physics.
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