M. -T. Zhu, Y. -C. Chen, Y. Jiang, B. -Y. Hu, J. -R. Zhou, C. -L. Ni
{"title":"Syntheses, Characterization, Crystal Structures and Antimicrobial Properties of a New Organic-Inorganic Hybrid [4FBzTPP]2[CuBr4]","authors":"M. -T. Zhu, Y. -C. Chen, Y. Jiang, B. -Y. Hu, J. -R. Zhou, C. -L. Ni","doi":"10.1134/s0022476624070047","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>This article presents a study on the synthesis and character of a new organic-inorganic hybrid [4FBzTPP]<sub>2</sub>[CuBr<sub>4</sub>] (<b>1</b>) ([4FBzTPP]<sup>+</sup> is 4-fluorobenzyltriphenylphosphinium) by XRD, SEM, FTIR and UV-Vis. The XRD analysis showed that the hybrid <b>1</b> belongs to the triclinic space group <i>P</i>2<sub>1</sub> with <i>b = </i>8.8600(10) Å, <i>c =</i> 16.4867(17) Å, α<i> = </i>16.639(2)°, β<i> = </i>96.342(4)°, <i>V</i> = 2415.6(5) Å<sup>3</sup>, and <i>Z</i> = 2. The hybrid consists of two [4FBzTPP]<sup>+</sup> cations and one [CuBr<sub>4</sub>]<sup>2–</sup> anion, and the [CuBr<sub>4</sub>]<sup>2–</sup> exhibits a twisted tetrahedral coordination geometry with the average bond length between Cu–Br is 2.393 Å. The 3D network structure of <b>1</b> is formed by electrostatic terms and other intermolecular interactions. The hybrid material undergoes a direct optical transition and has energy gap values of 1.66 eV and 2.18 eV, indicating its potential as a semiconductor material for optical research. The hybrid material undergoes a direct optical transition and has energy gap values of 1.66 eV and 2.18 eV, showing that the hybrid material is a potential semiconductor material for optical research. In addition, the compound exhibited good antibacterial activity against<i> E. coli </i>and <i>S. aureus</i>.</p>","PeriodicalId":668,"journal":{"name":"Journal of Structural Chemistry","volume":null,"pages":null},"PeriodicalIF":1.2000,"publicationDate":"2024-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Structural Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1134/s0022476624070047","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
This article presents a study on the synthesis and character of a new organic-inorganic hybrid [4FBzTPP]2[CuBr4] (1) ([4FBzTPP]+ is 4-fluorobenzyltriphenylphosphinium) by XRD, SEM, FTIR and UV-Vis. The XRD analysis showed that the hybrid 1 belongs to the triclinic space group P21 with b = 8.8600(10) Å, c = 16.4867(17) Å, α = 16.639(2)°, β = 96.342(4)°, V = 2415.6(5) Å3, and Z = 2. The hybrid consists of two [4FBzTPP]+ cations and one [CuBr4]2– anion, and the [CuBr4]2– exhibits a twisted tetrahedral coordination geometry with the average bond length between Cu–Br is 2.393 Å. The 3D network structure of 1 is formed by electrostatic terms and other intermolecular interactions. The hybrid material undergoes a direct optical transition and has energy gap values of 1.66 eV and 2.18 eV, indicating its potential as a semiconductor material for optical research. The hybrid material undergoes a direct optical transition and has energy gap values of 1.66 eV and 2.18 eV, showing that the hybrid material is a potential semiconductor material for optical research. In addition, the compound exhibited good antibacterial activity against E. coli and S. aureus.
期刊介绍：
Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.
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