Comparison of cell morphology and mechanical properties of wheat straw powder/HDPE parts molded by supercritical fluid foamed injection with and without gas counter pressure technology

IF 3.2 4区 工程技术 Q2 ENGINEERING, CHEMICAL
Xi‐long Jiang, Xing‐yuan Chen, Fang‐Fang Wang, Ming‐yuan Chien, Hai‐mei Li
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引用次数: 0

Abstract

Composites were fabricated using maleic anhydride‐grafted high‐density polyethylene as the matrix material and wheat straw as the filler. Differential scanning calorimetry and rheological properties of these composites were investigated to determine the processing parameters for supercritical fluid (SCF) microcellular injection with and without gas counter pressure (GCP) technology. The impacts of different proportions and dimensions of wheat straw, along with process parameters related to GCP, were determined on both the cellular structure and mechanical characteristics of foamed injection molded components. Experimental results revealed that an increase in the ratio of wheat straw and a reduction in its size led to enhancements in both storage modulus and complex viscosity of the composites, while also improving their cell structure when foamed with SCF. By adjusting GCP process parameters, it was possible to regulate both cell morphology and mechanical properties of foamed injection molded parts. Higher GCP or longer GCP holding time resulted in increased skin thickness and tensile strength but decreased notched Izod impact strength.Highlights Built relations between GCP technology parameters and cell morphologies. Compared the influence of wheat straw powder and GCP parameters quantitatively. Explored the correlation between cellular morphology and mechanical properties. The regulatory mechanism of cell morphology, size ratio, and distribution. GCP effectively modulates cell morphologies and mechanical properties.
采用超临界流体发泡注塑技术和不采用气体反压技术成型的小麦秸秆粉/高密度聚乙烯部件的细胞形态和机械性能比较
以马来酸酐接枝高密度聚乙烯为基体材料,以小麦秸秆为填料,制作了复合材料。研究了这些复合材料的差示扫描量热法和流变特性,以确定采用或不采用气体反压(GCP)技术的超临界流体(SCF)微孔注射的加工参数。实验确定了不同比例和尺寸的小麦秸秆以及与 GCP 相关的工艺参数对发泡注塑部件的蜂窝结构和机械特性的影响。实验结果表明,增加小麦秸秆的比例和减小其尺寸可提高复合材料的储存模量和复合粘度,同时还能改善用 SCF 发泡时的蜂窝结构。通过调整 GCP 工艺参数,可以调节发泡注塑件的细胞形态和机械性能。更高的 GCP 或更长的 GCP 保持时间可增加表皮厚度和拉伸强度,但会降低缺口伊佐德冲击强度。定量比较了小麦秸秆粉和 GCP 参数的影响。探索细胞形态与力学性能的相关性。细胞形态、大小比例和分布的调控机制。GCP 可有效调节细胞形态和力学性能。
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来源期刊
Polymer Engineering and Science
Polymer Engineering and Science 工程技术-高分子科学
CiteScore
5.40
自引率
18.80%
发文量
329
审稿时长
3.7 months
期刊介绍: For more than 30 years, Polymer Engineering & Science has been one of the most highly regarded journals in the field, serving as a forum for authors of treatises on the cutting edge of polymer science and technology. The importance of PE&S is underscored by the frequent rate at which its articles are cited, especially by other publications - literally thousand of times a year. Engineers, researchers, technicians, and academicians worldwide are looking to PE&S for the valuable information they need. There are special issues compiled by distinguished guest editors. These contain proceedings of symposia on such diverse topics as polyblends, mechanics of plastics and polymer welding.
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