Rotational Isomerism of Amide Units in the Ring of Rotaxanes in Response to Base/Acid Stimuli

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2024-07-25 DOI:10.1093/chemle/upae143

Takanori Nakamura, Yukari Okuma, Shinobu Miyagawa, Tsuneomi Kawasaki, Masaya Naito, Yuji Tokunaga

引用次数: 0

Abstract

Rotational isomerism of four amide moieties of the threaded macrocyclic component of [2]rotaxanes featuring mono- and bis-ammonium moieties in dumbbell-shaped axle components were investigated in response to base, and the rotational isomerization of both rotaxanes could be controlled reversibly through the addition of appropriate amounts of base and acids.

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在碱/酸刺激下旋吐烷环中酰胺单元的旋转异构现象

研究了哑铃形轴心成分中具有单铵和双铵的 [2]rotaxanes 的螺纹大环成分的四个酰胺分子在碱作用下的旋转异构现象，通过加入适量的碱和酸，可以可逆地控制这两种 rotaxanes 的旋转异构化。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.