Innovative Photocatalytic Reactor for Sustainable Industrial Water Decontamination: Utilizing 3D-Printed Components and Silica-Titania Trilayer Coatings

George V. Theodorakopoulos, Michalis K. Arfanis, Tadej Stepišnik Perdih, Simos Malamis, Dimitrios Iatrou, George Em. Romanos, Polycarpos Falaras
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Abstract

Industrial activities generate enormous quantities of polluted effluents, necessitating advanced methods of wastewater treatment to prevent potential environmental threats. Thus, the design of a novel photocatalytic reactor for industrial water decontamination, purification, and reuse is proposed as an efficient advanced oxidation technology. In this work, the development of the active reactor components is described, utilizing a two-step sol–gel technique to prepare a silica-titania trilayer coating on 3D-printed polymeric filters. The initial dip-coated SiO2 insulator further protects and enhances the stability of the polymer matrix, and the subsequent TiO2 layers endow the composite architecture with photocatalytic functionality. The structural and morphological characteristics of the modified photocatalytic filters are extensively investigated, and their performance is assessed by studying the photocatalytic degradation of the Triton X-100, a common and standard chemical surfactant, presented in the contaminated wastewater of the steel metal industry. The promising outcomes of the innovative versatile reactor pave the way for developing scalable, cost-effective reactors for efficient water treatment technologies.
用于可持续工业用水净化的创新型光催化反应器:利用三维打印部件和二氧化硅-钛三层涂层
工业活动会产生大量的污染废水,因此需要采用先进的废水处理方法来防止潜在的环境威胁。因此,我们提出设计一种新型光催化反应器,作为一种高效的高级氧化技术,用于工业用水的去污、净化和回用。这项工作介绍了活性反应器组件的开发,利用两步溶胶-凝胶技术在 3D 打印聚合物过滤器上制备二氧化硅-钛三层涂层。最初浸涂的二氧化硅绝缘体可进一步保护和增强聚合物基体的稳定性,而随后的二氧化钛层则赋予了复合结构光催化功能。我们广泛研究了改性光催化过滤器的结构和形态特征,并通过研究钢铁金属工业污染废水中常见的标准化学表面活性剂 Triton X-100 的光催化降解来评估其性能。创新型多功能反应器取得的可喜成果为开发可扩展的、具有成本效益的高效水处理技术反应器铺平了道路。
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