A New Approach to Determining the Blending Octane Number of Gaseous Components of Motor Gasolines

IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY
E. B. Kovaleva, S. G. Dyachkova, A. A. Ganina, I. E. Kuzora, V. A. Sergeev
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Abstract

The octane number for gaseous components (GC) is currently determined using the calculation method proceeding from the hydrocarbon composition. The method provides determination of the research octane number (RON) only. A discrepancy between the actual and predicted values of the octane number thus determined leads to an overestimated introduction of these components into the fuel which results in the reduced fuel performance and economic indicators of the production. In this regard, the development of a new approach to the determination of the blending octane number of low-boiling components is extremely important for designing optimal formulations of motor fuels. A method for determining the blending octane numbers (both RON and MON) of motor gasoline gaseous components has been improved owing to preliminary sample preparation by bubbling which provided taking into account the proportion of involvement of fractions of C4 hydrocarbon and pentane–amylene along with the chemical nature of the base fuel components. It is shown that the value of the blending octane number for gaseous components depends on the hydrocarbon composition of the base component. Application of the developed method to determining the blending octane number of gaseous components of motor fuels allowed us to obtain optimal formulations of gasoline with the involvement of low-boiling by-products and increase the accuracy of forecasting the composition of fuels, thus improving the economic performance of the production.

Abstract Image

确定车用汽油气体成分混合辛烷值的新方法
摘要目前,气态成分(GC)的辛烷值是通过碳氢化合物组成的计算方法确定的。这种方法只能确定研究辛烷值 (RON)。如果确定的辛烷值的实际值与预测值不一致,就会导致高估燃料中这些成分的含量,从而降低燃料性能和生产的经济指标。因此,开发一种新的方法来确定低沸点成分的混合辛烷值,对于设计最佳的汽车燃料配方极为重要。通过气泡法进行初步样品制备,考虑到 C4 碳氢化合物和戊烷-亚甲基馏分的参与比例以及基础燃料成分的化学性质,确定车用汽油气态成分调和辛烷值(RON 和 MON)的方法得到了改进。结果表明,气体成分的混合辛烷值取决于基础成分的碳氢化合物组成。应用所开发的方法来确定汽车燃料中气体成分的混合辛烷值,使我们能够获得含有低沸点副产品的最佳汽油配方,并提高预测燃料成分的准确性,从而改善生产的经济效益。
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来源期刊
Inorganic Materials
Inorganic Materials 工程技术-材料科学:综合
CiteScore
1.40
自引率
25.00%
发文量
80
审稿时长
3-6 weeks
期刊介绍: Inorganic Materials is a journal that publishes reviews and original articles devoted to chemistry, physics, and applications of various inorganic materials including high-purity substances and materials. The journal discusses phase equilibria, including P–T–X diagrams, and the fundamentals of inorganic materials science, which determines preparatory conditions for compounds of various compositions with specified deviations from stoichiometry. Inorganic Materials is a multidisciplinary journal covering all classes of inorganic materials. The journal welcomes manuscripts from all countries in the English or Russian language.
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