Accretion of Meteoric Organic Matter at the Surface of Mars and Potential Production of Methane by Ultraviolet Radiation

Abstract

In this study, a comprehensive model of the meteoric organic cycle on Mars for the current geological period is developed, which characterizes the ablation of exogenous organic matter in the upper atmosphere, the accretion of intact carbon at the surface, and the potential production of methane by UV photolysis from the surface reservoir. The model accounts for both the latitudinal and seasonal variation of the meteoroids’ input from the most relevant populations in the inner solar system. A recent version of the University of Leeds Chemical Ablation Model, which includes a semiempirical model to describe the pyrolysis kinetics of the meteoric organic matter, is then combined with this meteoroid input function and a semiempirical model that quantifies the UV production of methane. The minimum and maximum accretion rates of organics are between 18 and 90 kg sol−1 at aphelion and 45–134 kg sol−1 at the first crossing of the ecliptic plane. The resulting mixing ratios of carbon, in the top 200 μm of the surface layer, range from 0.09–0.43 ppm at 20°N to 4.8–8.9 ppm around the south pole. To be consistent with the methane upper limit of 0.02 ppbv measured by the NOMAD instrument on the ExoMars Trace Gas Orbiter, the UV photolysis yields for methane production need to be around 3% assuming a meteoric carbon content in comets of 25.6 wt% and an atmospheric lifetime of methane of 329 Earth yr. Alternatively, a laboratory estimate of 20% for the methane production yield would require a lifetime of 60 Earth yr.