Hydrochar production through co-hydrothermal carbonization of water hyacinth and plastic waste

M. Y. Ong, S. Nomanbhay, C. U. A. A. C. Rosman, T. Yusaf, A. S. Silitonga
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Abstract

The global expansion of the economy and concerns about greenhouse gas emissions and climate change necessitate the exploration of sustainable alternatives to fossil fuels. Water hyacinth (WH) is globally recognized as one of the most problematic aquatic weeds, posing significant challenges to urban management by clogging waterways, polluting water sources, and causing harm to ecosystems. However, water hyacinth is enriched with hemicellulose, cellulose, and lignin, making it a noteworthy and superior biomass resource. Hence, this study focuses on the hydrothermal carbonization of water hyacinth into a renewable fuel source, the hydrochar. Hydrothermal treatment was implemented in this work as it can treat wet biomass, in this case, the water hyacinth, without the need of energy-extensive drying process. Plastic waste (PW), or more specifically low-density polyethylene (LDPE), was added as the co-feedstock during the HTC process with the purpose to boost the higher heating value (HHV) of the end product. The co-hydrothermal carbonization (co-HTC) process of the mixture of WH and PW at various ratios and temperatures were conducted to investigate the optimal HTC condition for high hydrochar yields. As the result, the highest hydrochar yield of 29.23 wt% was obtained with 12.5% LDPE substitution percentage, at 200 °C after a holding time of 90 min. However, in term of energy recovery efficiency (ER), the highest efficiency (27.28%) was achieved with 12.5% LDPE substitution percentage at 260 °C. The HHV value of the hydrochar produced in this work is in the range of 17.71-24.69 MJ/kg. In summary, the co-HTC of WH and LDPE could definitely be a promising alternative to bridge the gap from solid waste to renewable fuels.
通过对布袋莲和塑料废弃物进行共热碳化生产水碳
随着全球经济的发展以及对温室气体排放和气候变化的担忧,有必要探索化石燃料的可持续替代品。布袋莲(WH)是全球公认的最棘手的水生杂草之一,它堵塞水道、污染水源、危害生态系统,给城市管理带来了巨大挑战。然而,布袋莲富含半纤维素、纤维素和木质素,是一种值得关注的优质生物质资源。因此,本研究的重点是通过水热碳化将布袋莲转化为一种可再生燃料--水碳。本研究采用水热处理法,因为它可以处理湿生物质(本例中为布袋莲),而无需耗费大量能源进行干燥处理。塑料废料(PW),更具体地说是低密度聚乙烯(LDPE),被添加到 HTC 过程中作为辅助原料,目的是提高最终产品的较高热值(HHV)。在不同比例和温度下对 WH 和 PW 混合物进行了共氢热碳化(co-HTC)过程,以研究获得高水炭产率的最佳 HTC 条件。结果表明,在 200 °C 下,保温 90 分钟后,当低密度聚乙烯替代率为 12.5% 时,获得了 29.23 wt% 的最高水碳产率。然而,就能量回收效率(ER)而言,12.5% 的低密度聚乙烯替代率在 260 °C 时的效率最高(27.28%)。本研究中生产的水碳的 HHV 值范围为 17.71-24.69 MJ/kg。总之,WH 和 LDPE 的共氢化碳氢化合物无疑是一种很有前途的替代品,可以弥补从固体废物到可再生燃料之间的差距。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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