Recent Developments in the Use of Spinel Ferrite Nanoparticles as Catalysts in Organic Reactions

Babul Kalita, Saddam Iraqui, Gariyasee Dutta, Md. Harunar Rashid
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Abstract

The unique physicochemical properties, low cost, low toxicity, and size- and shape-dependent magnetic properties of the ferrite-based nanoparticles make them an indispensable choice of material for various applications, including catalysis. The objective of this review is to summarize the results of the most widely used ferrite nanoparticles such as NiFe2O4, CuFe2O4, CoFe2O4, ZnFe2O4, and MnFe2O4 as catalysts in organic reactions such as C–X (X = N, O, and S) coupling, oxidation, and N-heterocycles formation reactions. This review includes a well-summarized compilation of the most widely used nanostructured ferrites such as NiFe2O4, CuFe2O4, CoFe2O4, ZnFe2O4, and MnFe2O4 as heterogeneous catalysts in selected organic reactions such as C–X (X = N, O, and S) coupling, oxidation, and N-heterocycles formation reactions. The nanostructured magnetic ferrite catalysts are reliable and extremely effective and facilitate the quick separation of catalysts, making the process sustainable. The presentation of the review has been proposed anticipating new perspectives and insight in the field of catalysis and investigate further development of novel ferrite materials on an industrial scale for practical applications.
将尖晶石铁氧体纳米颗粒用作有机反应催化剂的最新进展
基于铁氧体的纳米颗粒具有独特的物理化学特性、低成本、低毒性以及尺寸和形状随磁性变化的特性,因此成为包括催化在内的各种应用中不可或缺的材料选择。本综述旨在总结最广泛使用的铁氧体纳米颗粒(如 NiFe2O4、CuFe2O4、CoFe2O4、ZnFe2O4 和 MnFe2O4)在有机反应(如 C-X(X = N、O 和 S)偶联、氧化和 N-杂环形成反应)中作为催化剂的研究成果。本综述对最广泛使用的纳米结构铁氧体(如 NiFe2O4、CuFe2O4、CoFe2O4、ZnFe2O4 和 MnFe2O4)进行了总结,这些纳米结构铁氧体可在特定有机反应(如 C-X(X = N、O 和 S)偶联、氧化和 N-杂环形成反应)中用作异相催化剂。纳米结构的磁性铁氧体催化剂性能可靠、极其有效,并能促进催化剂的快速分离,使反应过程具有可持续性。本综述旨在展望催化领域的新视角和新见解,并研究新型铁氧体材料在工业规模上的进一步发展和实际应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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