{"title":"Pseudocapacitive TiNb0.8O4 microspheres for fast-charging and durable sodium storage","authors":"Xinyuan Li, Tianyi Zhang, Zhuo Chen, Hao Fan, Ping Hu, Congcong Cai, Liang Zhou","doi":"10.1016/j.mtener.2024.101637","DOIUrl":null,"url":null,"abstract":"Titanium niobium oxides are promising anode materials for sodium-ion batteries (SIBs) due to their efficient ion diffusion channels. However, their poor electronic conductivity impedes the longevity of SIBs. To address these issues, core@shell TiNbO/C@C microspheres (TNO/C@C) have been developed to enhance electron conduction. The TNO/C@C, featuring a bulk and surface dual conductive configuration, outperforms pure TNO and other control samples such as TNO/C and TNO@C that rely solely on either bulk or surface electronic conductors. Thus, the TNO/C@C achieves a fast-charging rate of 200 C, allowing full charging in 2 s, and demonstrates long-term stability over 10,000 cycles. Raman analysis reveals a zero-strain feature during sodiation/desodiation, which minimizes structural degradation over repeated cycles. electrochemical impedance spectroscopy test indicates low electron resistance, enhancing both the rate capability and stability. Therefore, the bulk and surface dual conducting strategy offers new insights into robust and fast-charging SIBs.","PeriodicalId":18277,"journal":{"name":"Materials Today Energy","volume":"41 1","pages":""},"PeriodicalIF":9.0000,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Today Energy","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1016/j.mtener.2024.101637","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Titanium niobium oxides are promising anode materials for sodium-ion batteries (SIBs) due to their efficient ion diffusion channels. However, their poor electronic conductivity impedes the longevity of SIBs. To address these issues, core@shell TiNbO/C@C microspheres (TNO/C@C) have been developed to enhance electron conduction. The TNO/C@C, featuring a bulk and surface dual conductive configuration, outperforms pure TNO and other control samples such as TNO/C and TNO@C that rely solely on either bulk or surface electronic conductors. Thus, the TNO/C@C achieves a fast-charging rate of 200 C, allowing full charging in 2 s, and demonstrates long-term stability over 10,000 cycles. Raman analysis reveals a zero-strain feature during sodiation/desodiation, which minimizes structural degradation over repeated cycles. electrochemical impedance spectroscopy test indicates low electron resistance, enhancing both the rate capability and stability. Therefore, the bulk and surface dual conducting strategy offers new insights into robust and fast-charging SIBs.
期刊介绍:
Materials Today Energy is a multi-disciplinary, rapid-publication journal focused on all aspects of materials for energy.
Materials Today Energy provides a forum for the discussion of high quality research that is helping define the inclusive, growing field of energy materials.
Part of the Materials Today family, Materials Today Energy offers authors rigorous peer review, rapid decisions, and high visibility. The editors welcome comprehensive articles, short communications and reviews on both theoretical and experimental work in relation to energy harvesting, conversion, storage and distribution, on topics including but not limited to:
-Solar energy conversion
-Hydrogen generation
-Photocatalysis
-Thermoelectric materials and devices
-Materials for nuclear energy applications
-Materials for Energy Storage
-Environment protection
-Sustainable and green materials