Optothermal generation, steady-state trapping, and 3D manipulation of bubbles: an experimental and theoretical analysis of the Marangoni effect

Abstract

Since Nobel Laureate Arthur Ashkin first introduced the trapping and manipulation of microparticles using light, numerous studies have explored this technique not only for dielectric/metallic particles but also for organic matter. This advancement has significantly expanded the landscape of non-contact and non-invasive micromanipulation at the nanometric scale. However, micromanipulation of particles with a refractive index smaller than the host medium, np< nm, proves challenging with Gaussian beams. To overcome this obstacle, a force known as thermocapillary, or the Marangoni force, has emerged as a straightforward trapping mechanism for bubbles in liquids. The Marangoni force results from the surface tension of bubbles, induced either thermally or chemically—by creating a temperature gradient or adding surfactants, respectively. The surface tension gradient on the liquid host induces tangential stress on the bubble wall, causing the bubble to move toward the region of lower surface tension, where it faces less opposing force. When the Marangoni force is generated by a laser beam’s temperature gradient, it becomes an exceptionally effective mechanism for the steady-state trapping and three-dimensional manipulation of bubbles, even with low optical power lasers. This force produces both longitudinal and transversal forces, resembling optical forces, creating a three-dimensional potential well capable of handling bubbles with radii of tens to hundreds of microns. This work provides guidance and demonstrates, both experimentally and theoretically, the step-by-step process of quasi-steady-state trapping and three-dimensional manipulation of bubbles through optothermal effects. The bubbles in question are tens of microns in size, significantly larger than those that optical tweezers can trap/manipulate. Furthermore, the study emphasizes the crucial role of the Marangoni force in this process, outlining its various advantages.