Sea urchin inspired ultrafast response low humidity sensor based on ionic liquid modified UiO-66 with advanced applications

IF 9.7 1区 化学 Q1 CHEMISTRY, PHYSICAL
Ke Wu , Zhimin Yang , Sen Liu , Xishuang Liang , Teng Fei , Tong Zhang
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Abstract

Numerous applications require low humidity sensors that not only sensitive but also stable, small hysteresis, high resolution and fast response. However, most reported low humidity sensors cannot possess these properties at the same time. In this work, inspired by sea urchin, we developed an ionic liquid (IL) modified metal organic framework (UiO-66) based low humidity sensor. Owing to the synergistic effect of the hydrophilicity and ionic conductivity of IL and the steric hindrance effects of UiO-66, the optimized low humidity sensor simultaneously exhibits high response (47.5), small hysteresis (0.3 % RH), ultrafast response speed (0.2 s), high resolution (1 % RH), and excellent long-term stability (>120 days). In particular, the sensor has been proved to have potential applications in visual humidity detection and water source location. This work provides a preliminary design principle that will contribute to the preparation of high-performance low humidity sensing materials.

Abstract Image

基于离子液体改性 UiO-66 的海胆灵感超快响应低湿度传感器的先进应用。
许多应用要求低湿度传感器不仅灵敏,而且稳定、滞后小、分辨率高、响应快。然而,大多数已报道的低湿度传感器无法同时具备这些特性。在这项工作中,我们受海胆的启发,开发了一种基于离子液体(IL)修饰金属有机框架(UiO-66)的低湿度传感器。由于离子液体的亲水性和离子导电性与 UiO-66 的立体阻碍效应的协同作用,优化后的低湿度传感器同时表现出高响应(47.5)、小滞后(0.3 % RH)、超快响应速度(0.2 秒)、高分辨率(1 % RH)和优异的长期稳定性(大于 120 天)。特别是,该传感器已被证明在视觉湿度检测和水源定位方面具有潜在的应用价值。这项研究提供了初步的设计原理,有助于制备高性能的低湿度传感材料。
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来源期刊
CiteScore
16.10
自引率
7.10%
发文量
2568
审稿时长
2 months
期刊介绍: The Journal of Colloid and Interface Science publishes original research findings on the fundamental principles of colloid and interface science, as well as innovative applications in various fields. The criteria for publication include impact, quality, novelty, and originality. Emphasis: The journal emphasizes fundamental scientific innovation within the following categories: A.Colloidal Materials and Nanomaterials B.Soft Colloidal and Self-Assembly Systems C.Adsorption, Catalysis, and Electrochemistry D.Interfacial Processes, Capillarity, and Wetting E.Biomaterials and Nanomedicine F.Energy Conversion and Storage, and Environmental Technologies
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zirconium chloride (ZrCl4)
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1,2,4-benzenetricarboxylic acid
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2-nitroterephthalic acid
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cysteamine
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benzoin dimethyl ether (DMPA)
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N,N-dimethylformamide (DMF)
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glacial acetic acid
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methanol (CH3OH)
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ethanol (C2H5OH)
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toluene
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tetrahydrofuran (THF)
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phosphorus pentoxide
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lithium bromide (LiBr)
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lithium chloride (LiCl)
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potassium acetate (CH3COOK)
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magnesium chloride (MgCl2)
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